Electrochromic device and method for manufacturing electrochromic device
The invention relates to devices that provide a color change under the influence of an electric voltage, in particular to an electrochromic device and a method for manufacturing such a device. Disclosed is the method for manufacturing an electrochromic device comprising at least two electrodes that are flexible and optically transparent with a hermetically closed space between the electrodes filled with an electrochromic composition that may contain transparent and insoluble microparticles that function as spacers.
1. A method for manufacturing an electrochromic device comprising at least two flexible electrodes and a hermetically closed space between the at least two flexible electrodes, at least one of the at least two flexible electrodes being optically transparent, wherein the hermetically closed space between the at least two flexible electrodes is filled with an electrochromic composition, the method comprising:
(1) preparing an initial deaerated electrochromic composition in the form of an electrochromic dispersion system containing a colloid,
wherein a continuous phase of the electrochromic dispersion system comprises,
an electrochromic solution comprising a liquid solvent,
a cathodic component,
an anodic component,
a polymerizable low-shrinkage monomer or a monomer mixture comprising a cationic ring-openable polymerization monomer, and
a polymerization thermal activator,
wherein a non-continuous phase, of said electrochromic dispersion system, consists of a dispersible polymer, wherein said non-continuous phase is said colloid, and
wherein the initial electrochromic composition is deaerated to remove the dissolved oxygen of air that were introduced with the dispersible polymer;
(2) filling the hermetically closed space between the at least two flexible electrodes with the deaerated initial electrochromic composition; and
(3) sealing the hermetically closed space between the at least two flexible electrodes.