Aluminum alloy clad material
An aluminum alloy clad material includes: a sacrificial material on one surface of a core material; and an Al—Si—Mg—Bi-based brazing material disposed on other surface of the core material, contains, by mass %, Si: 6.0% to 14.0%, Mg: 0.05% to 1.5%, Bi: 0.05% to 0.25%, Sr: 0.0001% to 0.1%, and a balance consisting of Al and inevitable impurities, and satisfies a relationship of (Bi+Mg)×Sr≤0.1 by mass %, in which Mg—Bi-based compounds contained in the Al—Si—Mg—Bi-based brazing material with a diameter of 0.1 μm or more and less than 5.0 μm are more than 20 in number per 10,000-μm 2 and the Mg—Bi-based compounds with a diameter of 5.0 μm or more are less than 2 in number, and the core material contains Mn: 0.9% to 1.7%, Si: 0.2% to 1.0%, Fe: 0.1% to 0.5%, Cu: 0.08% to 1.0%, and a balance consisting of Al and inevitable impurities.
1. An aluminum alloy clad material comprising three layers comprising:
a sacrificial material disposed on one surface of a core material; and
an Al—Si—Mg—Bi brazing material which is disposed on the other surface of the core material, comprising, by mass %, from 6.0% to 14.0% of Si, from 0.05% to 1.5% of Mg, from 0.05% to 0.25% of Bi, from 0.0001% to 0.1% of Sr, and a balance consisting of Al and inevitable impurities, and satisfying a relationship of (Bi+Mg)×Sr≤0.1 in amounts of elements by mass %,
wherein the Al—Si—Mg—Bi brazing material comprises more than 20 in number per 10,000-μm 2 visual field of Mg—Bi compounds having a diameter of from 0.1 μm to less than 5.0 μm, in terms of equivalent circle diameter and less than 2 in number per 10,000-μm 2 visual field of the Mg—Bi compounds having a diameter of 5.0 μm or more, when observed in a surface layer plane direction before brazing, and
wherein the core material comprises, by mass %, from 0.9% to 1.7% of Mn, from 0.2% to 1.0% of Si, from 0.1% to 0.5% of Fe, from 0.08% to 1.0% of Cu, and a balance consisting of Al and inevitable impurities.
2. The aluminum alloy clad material according to claim 1 , wherein the core material further comprises from 0.1% to 0.7% of Mg and comprises a balance consisting of Al and inevitable impurities.
3. The aluminum alloy clad material according to claim 1 , wherein the core material further comprises from 0.05% to 0.3% of Ti and comprises a balance consisting of Al and inevitable impurities.
4. The aluminum alloy clad material according to claim 2 , wherein the core material further comprises from 0.05% to 0.3% of Ti and comprises a balance consisting of Al and inevitable impurities.
5. The aluminum alloy clad material according to claim 1 , wherein a concentration of Mg on a surface of the brazing material at a braze melting temperature is from 0.15% to 1.0%.
6. The aluminum alloy clad material according to claim 2 , wherein a concentration of Mg on a surface of the brazing material at a braze melting temperature is from 0.15% to 1.0%.
7. The aluminum alloy clad material according to claim 3 , wherein a concentration of Mg on a surface of the brazing material at a braze melting temperature is from 0.15% to 1.0%.
8. The aluminum alloy clad material according to claim 4 , wherein a concentration of Mg on a surface of the brazing material at a braze melting temperature is from 0.15% to 1.0%.
9. The aluminum alloy clad material according to claim 1 , wherein the sacrificial material comprises, by mass %, at least one of from 0.2% to 6.0% of Zn, from 0.3% to 1.3% of Mn, from 0.2% to 0.8% of Si from 0.02% to 0.3% of Mg, from 0.2% to 0.8% of Fe, from 0.05% to 0.5% of Cr, and from 0.05% to 0.3% of Ti, and comprises a balance consisting of Al and inevitable impurities, and
a concentration of Cu on a surface of the sacrificial material after brazing is 0.12% or less.
10. The aluminum alloy clad material according to claim 2 , wherein the sacrificial material comprises, by mass %, at least one of from 0.2% to 6.0% of Zn, from 0.3% to 1.3% of Mn, from 0.2% to 0.8% of Si, from 0.02% to 0.3% of Mg, from 0.2% to 0.8% of Fe, from 0.05% to 0.5% of Cr, and from 0.05% to 0.3% of Ti, and comprises a balance consisting of Al and inevitable impurities, and
a concentration of Cu on a surface of the sacrificial material after brazing is 0.12% or less.
11. The aluminum alloy clad material according to claim 3 , wherein the sacrificial material comprises, by mass %, at least one of from 0.2% to 6.0% of Zn, from 0.3% to 1.3% of Mn, from 0.2% to 0.8% of Si, from 0.02% to 0.3% of Mg, from 0.2% to 0.8% of Fe, from 0.05% to 0.5% of Cr, and from 0.05% to 0.3% of Ti, and comprises a balance consisting of Al and inevitable impurities, and
a concentration of Cu on a surface of the sacrificial material after brazing is 0.12% or less.
12. The aluminum alloy clad material according to claim 4 , wherein the sacrificial material comprises, by mass %, at least one of from 0.2% to 6.0% of Zn, from 0.3% to 1.3% of Mn, from 0.2% to 0.8% of Si, from 0.02% to 0.3% of Mg, from 0.2% to 0.8% of Fe, from 0.05% to 0.5% of Cr, and from 0.05% to 0.3% of Ti, and comprises a balance consisting of Al and inevitable impurities, and
a concentration of Cu on a surface of the sacrificial material after brazing is 0.12% or less.
13. The aluminum alloy clad material according to claim 5 , wherein the sacrificial material comprises, by mass % at least one of from 0.2% to 6.0% of Zn, from 0.3% to 1.3% of Mn, from 0.2% to 0.8% of Si, from 0.02% to 0.3% of Mg, from 0.2% to 0.8% of Fe, from 0.05% to 0.5% of Cr, and from 0.05% to 0.3% of Ti, and comprises a balance consisting of Al and inevitable impurities, and
a concentration of Cu on a surface of the sacrificial material after brazing is 0.12% or less.
14. The aluminum alloy clad material according to claim 6 , wherein the sacrificial material comprises, by mass %, at least one from 0.2% to 6.0% of Zn, from 0.3% to 1.3% of Mn, from 0.2% to 0.8% of Si from 0.02% to 0.3% of Mg, from 0.2% to 0.8% of Fe, from 0.05% to 0.5% of Cr, and from 0.05% to 0.3% of Ti, and comprises a balance consisting of Al and inevitable impurities, and
a concentration of Cu on a surface of the sacrificial material after brazing is 0.12% or less.
15. The aluminum alloy clad material according to claim 7 , wherein the sacrificial material comprises, by mass %, at least one of from 0.2% to 6.0% of Zn, from 0.3% to 1.3% of Mn, from 0.2% to 0.8% of Si, from 0.02% to 0.3% of Mg, from 0.2% to 0.8% of Fe, from 0.05% to 0.5% of Cr and from 0.05% to 0.3% of Ti, and comprises a balance consisting of Al and inevitable impurities, and
a concentration of Cu on a surface of the sacrificial material after brazing is 0.12% or less.
16. The aluminum alloy clad material according to claim 8 , wherein the sacrificial material comprises, by mass %, at least one of from 0.2% to 6.0% of Zn, from 0.3% to 1.3% of Mn, from 0.2% to 0.8% of Si, from 0.02% to 0.3% of Mg, from 0.2% to 0.8% of Fe, from 0.05% to 0.5% of Cr, and from 0.05% to 0.3% of Ti, and comprises a balance consisting of Al and inevitable impurities, and
a concentration of Cu on a surface of the sacrificial material after brazing is 0.12% or less.
17. The aluminum alloy clad material according to claim 1 , wherein the Al—Si—Mg—Bi brazing material comprises, by mass %, from 0.1% to 1.5% of Mg.
18. The aluminum alloy clad material according to claim 1 , wherein the Al—Si—Mg—Bi brazing material comprises, by mass %, from 0.2% to 1.5% of Mg.