Infrared-cut filter
A composition for infrared-absorbing layers according to the present invention includes: a compound formed by copper ion and a phosphonic acid represented by the following formula (a); and at least one of a phosphoric acid diester represented by the following formula (b1) and a phosphoric acid monoester represented by the following formula (b2). In the composition, fine particles containing at least the compound are dispersed. A content of the phosphonic acid is less than 2.5 times a total content of the phosphoric acid diester and the phosphoric acid monoester on a molar basis. R 1 is an alkyl group with 2 to 4 carbon atoms, R 21 , R 22 , and R 3 are each a monovalent functional group represented by —(CH 2 CH 2 O) n R 4 wherein n is an integer of 1 to 25 and R 4 is an alkyl group with 6 to 25 carbon atoms.
1. An infrared-cut filter comprising:
a first infrared-absorbing layer comprising:
a compound including a copper ion and a phosphonic acid represented by the following formula (a); and at least one phosphoric acid ester selected from the group consisting of phosphoric acid esters represented by the following formulae (b1) and (b2), wherein
a first molar ratio of a content of phosphorus to a content of copper is within a range of 1.22 to 1.53,
a second molar ratio of a content of the phosphonic acid to a content of the phosphoric acid esters is 0.85 or more and less than 2.50, and
a third molar ratio of a content of the phosphonic acid to a content of copper is within a range of 0.45 to 0.9,
wherein R 1 is an alkyl group with 2 to 4 carbon atoms, R 21 , R 22 and R 3 are each a monovalent functional group represented by —(CH 2 CH 2 O) n R 4 , n is an integer of 1 to 25, R 4 is an alkyl group with 6 to 25 carbon atoms, and R 21 , R 22 and R 3 are same or different functional group.
2. The infrared-cut filter according to claim 1 , wherein the first infrared-absorbing layer has a thickness of 40 μm to 250 μm.
3. The infrared-cut filter according to claim 1 , wherein the compound includes fine particles having an average particle diameter of 5 nm to 200 nm.
4. The infrared-cut filter according to claim 1 , wherein the first infrared-absorbing layer further comprises a matrix resin containing a polysiloxane.
5. The infrared-cut filter according to claim 1 , further comprising:
an anti-reflection film provided on the first infrared-absorbing layer.
6. The infrared-cut filter according to claim 1 , the infrared-cut filter further comprising a second infrared-absorbing layer and
an intermediate protective layer,
wherein the infrared-cut filter comprises, in sequence, the first infrared-absorbing layer, the intermediate protective layer, and the second infrared-absorbing layer.
7. The infrared-cut filter according to claim 6 , wherein the infrared-cut filter exhibits a transmittance of 80% or more over an entire wavelength range from 400 nm to 600 nm, and the infrared-cut filter exhibits a transmittance of 2% or less over an entire wavelength range from 800 nm to 1100 nm.
8. The infrared-cut filter according to claim 6 , wherein the intermediate protective layer includes a hydrolysis-condensation product of an alkoxysilane.
9. The infrared-cut filter according to claim 1 , wherein
the infrared-cut filter exhibits a transmittance of 70% or more over an entire wavelength range from 400 nm to 600 nm, and
the infrared-cut filter exhibits a transmittance 5% or less over an entire wavelength range from 800 nm to 1000 nm.
10. The infrared-cut filter according to claim 9 , wherein
the infrared-cut filter has a spectral transmittance of 90% or more at a wavelength of 570 nm.
11. The infrared-cut filter according to claim 1 , wherein
the infrared-cut filter has a spectral transmittance of 75% or more at a wavelength of 400 nm.