IP Library › Granted Patent US 11,605,833
Granted Patent B2
US 11,605,833 · App. 16/935,182 · Granted Mar 14, 2023

Solid electrolyte composition and method of manufacturing the same, solid electrolyte-containing sheet, electrode sheet for all-solid state secondary battery, and method of manufacturing all-solid state secondary battery

Inventors: Hiroshi Isojima (Kanagawa, JP); Shin Ozawa (Kanagawa, JP)
Assignee: FUJIFILM Corporation
H01M10/0562H01M4/139H01M4/62H01M2300/0068
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Quick Facts
Patent No.
US 11,605,833
App. No.
16/935,182
Granted
Mar 14, 2023
Kind
B2
Abstract

Provided are a solid electrolyte composition including an inorganic solid electrolyte and a dispersion medium (A), in which the dispersion medium (A) includes a ketone compound (A1), and at least one dispersant (A2) selected from a ketone compound (A2-1) having a chemical structure different from the ketone compound (A1) or a alcohol compound (A2-2) and a method of manufacturing the same, a solid electrolyte-containing sheet, an electrode sheet for an all-solid state secondary battery, and a method of manufacturing an all-solid state secondary battery.

Claims (26)

1. A solid electrolyte composition comprising:

an inorganic solid electrolyte; and

a dispersion medium (A), wherein the dispersion medium (A) includes a ketone compound (A1), and at least one dispersant (A2) selected from a ketone compound (A2-1) having a chemical structure different from the ketone compound (A1) or an alcohol compound (A2-2), the ketone compound (A1) has 6 or more carbon atoms, the ketone compound (A2-1) has 6 or more carbon atoms, and the alcohol compound (A2-2) has 6 or more carbon atoms.

2. The solid electrolyte composition according to claim 1 , further comprising an active material.

3. The solid electrolyte composition according to claim 1 , further comprising a conductive auxiliary agent.

4. The solid electrolyte composition according to claim 1 , wherein a content ratio of the dispersant (A2) in the dispersion medium (A) is more than 0% by mass and less than 50% by mass.

5. The solid electrolyte composition according to claim 1 , wherein the ketone compound (A2-1) has 9 or more carbon atoms.

6. The solid electrolyte composition according to claim 1 , wherein at least one dispersant (A2) is a structural isomer of the ketone compound (A1).

7. The solid electrolyte composition according to claim 1 , wherein the dispersion medium (A) includes at least one non-polar dispersant.

8. The solid electrolyte composition according to claim 1 , wherein a median diameter of an active material is larger than a median diameter of the inorganic solid electrolyte.

9. A solid electrolyte-containing sheet having a layer formed of the solid electrolyte composition according to claim 1 .

10. A method of manufacturing a solid electrolyte composition comprising:

a step of dispersing an inorganic solid electrolyte in a dispersion medium (A),

wherein the dispersion medium (A) includes a ketone compound (A1), and at least one dispersant (A2) selected from a ketone compound (A2-1) having a chemical structure different from the ketone compound (A1) or an alcohol compound (A2-2), the ketone compound (A1) has 6 or more carbon atoms, the ketone compound (A2-1) has 6 or more carbon atoms, and the alcohol compound (A2-2) has 6 or more carbon atoms.

11. The method of manufacturing a solid electrolyte composition according to claim 10 , wherein a content ratio of the dispersant (A2) in the dispersion medium (A) is more than 0% by mass and less than 50% by mass.

12. The method of manufacturing a solid electrolyte composition according to claim 10 , wherein the ketone compound (A2-1) has 9 or more carbon atoms.

13. The method of manufacturing a solid electrolyte composition according to claim 10 , wherein at least one dispersant (A2) is a structural isomer of the ketone compound (A1).

14. The method of manufacturing a solid electrolyte composition according to claim 10 , wherein the dispersion medium (A) includes at least one non-polar dispersant.

15. The method of manufacturing a solid electrolyte composition according to claim 10 , further comprising a step of mixing an active material and a preliminary dispersion obtained after the dispersing step.

16. The method of manufacturing a solid electrolyte composition according to claim 15 , wherein the mixing step is a step of mixing the preliminary dispersion, the active material, and a conductive auxiliary agent.

17. A method of manufacturing an electrode sheet for an all-solid state secondary battery comprising the method of manufacturing a solid electrolyte composition according to claim 10 .

18. A method of manufacturing an all-solid state secondary battery comprising the method of manufacturing a solid electrolyte composition according to claim 10 .

19. The method of manufacturing an all-solid state secondary battery according to claim 18 , wherein a solid electrolyte composition and a solid electrolyte composition containing an active material are simultaneously applied for multi-layer coating to form a solid electrolyte layer and an active material layer, and

at least one of the solid electrolyte composition or the solid electrolyte composition containing the active material is manufactured by a method of manufacturing a solid electrolyte composition comprising:

a step of dispersing an inorganic solid electrolyte in a dispersion medium (A),

wherein the dispersion medium (A) includes a ketone compound (A1), and at least one dispersant (A2) selected from a ketone compound (A2-1) having a chemical structure different from the ketone compound (A1) or an alcohol compound (A2-2), the ketone compound (A1) has 6 or more carbon atoms, the ketone compound (A2-1) has 6 or more carbon atoms, and the alcohol compound (A2-2) has 6 or more carbon atoms.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 30, 2020
From: ISOJIMA, HIROSHI; OZAWA, SHIN
To: FUJIFILM CORPORATION
Reel/Frame 053348/0873 →
Priority Claims (2)
JP JP2018-018676 · Feb 5, 2018 · national
JP JP2018-098992 · May 23, 2018 · national
Continuity (2)
Continuation PCTJP2019003298 · Jan 31, 2019
Related Publication 20200350628A1 · Nov 5, 2020
Cited By (4)
US 12,614,752 US 12,683,157 US 12,683,159 US 12,744,215