Pyrromethene-boron complex, color-changing composition, color-changing film, light source unit including same, display, and lighting

1. A color conversion composition for converting incident light into light having longer wavelength than the incident light, wherein the color conversion composition comprises a compound represented by formula (1) and a binder resin:

wherein

X is C—R 7 ,

each of R 1 , R 3 , R 4 and R 6 , which may be the same as or different from one another, is hydrogen, a halogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl ether group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted aryl thioether group, a substituted or unsubstituted amino group, a substituted or unsubstituted silyl group, or a cyano group,

R 2 and R 5 , which may be the same as or different from one another, is selected from hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkenyl group, a substituted or unsubstituted alkynyl group, a hydroxyl group, a thiol group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted aryl ether group, a substituted or unsubstituted aryl thioether group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heteroaryl group, a halogen, a cyano group, an aldehyde group, a substituted or unsubstituted carbonyl group, a carboxyl group, a substituted or unsubstituted oxycarbonyl group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted ester group, a substituted or unsubstituted sulfonyl group, a substituted or unsubstituted amide group, a substituted or unsubstituted amino group, a nitro group, a substituted or unsubstituted silyl group, a substituted or unsubstituted siloxanyl group, a substituted or unsubstituted boryl group, and a substituted or unsubstituted phosphine oxide group,

R 7 is either a substituted or unsubstituted aryl group or a substituted or unsubstituted heteroaryl group, and R 7 is represented by formula (2):

wherein

r is a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group,

k is an integer of 1 to 3, and

when k is 2 or more, r may be the same as or different from one another, and

each of R 8 and R 9 , which may be the same as or different from one another, is selected from a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkenyl group, a substituted or unsubstituted alkynyl group, a hydroxyl group, a thiol group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted aryl ether group, a substituted or unsubstituted aryl thioether group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heteroaryl group, and a halogen.

2. The color conversion composition according to claim 1 , wherein in formula (2), r is a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, or a halogen.

3. The color conversion composition according to claim 1 , wherein in formula (2), k is 1 or 2.

4. The color conversion composition according to claim 1 , wherein at least one of R 1 , R 3 , R 4 and R 6 is a substituted or unsubstituted alkyl group.

5. The color conversion composition according to claim 1 , wherein the compound represented by formula (1) emits light having a peak wavelength observed in the region of 500 to 580 nm, by use of excitation light.

6. The color conversion composition according to claim 1 , wherein the compound represented by formula (1) emits light having a peak wavelength observed in the region of 580 to 750 nm, by use of excitation light.

7. The color conversion composition according to claim 1 , wherein the color conversion composition comprises the following luminescent materials (a) and (b) and at least one of the luminescent materials (a) and (b) is a compound represented by formula (1):

(a) a luminescent material emitting light having a peak wavelength observed in the region of 500 to 580 nm by use of excitation light, and

(b) a luminescent material emitting light having a peak wavelength observed in the region of 580 to 750 nm upon excitation by at least either one of excitation light and luminescence from the luminescent material (a).

8. The color conversion composition according to claim 7 , wherein both of the luminescent materials (a) and (b) are a compound represented by formula (1).

9. The color conversion composition according to claim 7 , wherein a content w a of the luminescent material (a) and a content w b of the luminescent material (b) have a relationship of w a ≥w b .

10. The color conversion composition according to claim 1 , further comprising a solvent.

11. The color conversion composition according to claim 1 , wherein the binder resin is a thermoplastic resin.

12. A color conversion film comprising a layer comprising a cured product of the color conversion composition according to claim 1 .

13. The color conversion film according to claim 12 , further comprising a barrier film.

14. A light source unit comprising a light source and the color conversion film according to claim 12 .

15. The light source unit according to claim 14 , wherein the light source is a light-emitting diode having a maximum light emission in a range of 430 to 500 nm.

16. The light source unit according to claim 15 , wherein the light source is a light-emitting diode having a maximum light emission in a range of 450 to 470 nm.

17. The light source unit according to claim 14 , wherein the light source is a light-emitting diode having an emission peak wavelength in a range of 430 to 470 nm and an emission wavelength region in a range of 400 to 500 nm, and an emission spectrum of the light-emitting diode satisfies equation (1):

1>β/α≥;0.15  (1)

wherein

α is a light emission intensity at the emission wavelength peak of the emission spectrum, and

β is a light emission intensity at a wavelength of emission wavelength peak+15 nm.

18. A display comprising the color conversion film according to claim 12 .

19. A lighting comprising the color conversion film according to claim 12 .