Method for producing printed material and system for producing printed material
A method for producing a printed material includes forming a color image having an image area ratio of 20% or less on a peripheral edge portion of a recording medium by using a coloring material; providing pressure-induced phase transition particles to a region of the recording medium, the region including the peripheral edge portion; bonding the color image and the pressure-induced phase transition particles onto the recording medium; and folding the recording medium having the color image and the pressure-induced phase transition particles bonded thereon and pressure-bonding the folded recording medium, or pressure-bonding the recording medium having the color image and the pressure-induced phase transition particles bonded thereon and another recording medium placed on top of each other. The pressure-induced phase transition particles contain a styrene resin and a (meth)acrylic acid ester resin, the styrene resin contains styrene and a vinyl monomer other than styrene as polymerization components, the (meth)acrylic acid ester resin contains at least two (meth)acrylic acid esters as polymerization components, and a mass ratio of the (meth)acrylic acid esters is 90 mass % or more of a total of all polymerization components of the (meth)acrylic acid ester resin. The pressure-induced phase transition particles have at least two glass transition temperatures, and a difference between the lowest glass transition temperature and the highest glass transition temperature among the glass transition temperatures of the pressure-induced phase transition particles is 30° C. or more.
1. A method for producing a printed material, the method comprising:
forming a color image having an image area ratio of 20% or less on a peripheral edge portion of a recording medium by using a coloring material;
providing pressure-induced phase transition particles to a region of the recording medium, the region including the peripheral edge portion;
bonding the color image and the pressure-induced phase transition particles onto the recording medium; and
folding the recording medium having the color image and the pressure-induced phase transition particles bonded thereon and pressure-bonding the folded recording medium, or pressure-bonding the recording medium having the color image and the pressure-induced phase transition particles bonded thereon and another recording medium placed on top of each other,
wherein:
the pressure-induced phase transition particles contain a styrene resin and a (meth)acrylic acid ester resin, the styrene resin contains styrene and a vinyl monomer other than styrene as polymerization components, the (meth)acrylic acid ester resin contains at least two (meth)acrylic acid esters as polymerization components, and a mass ratio of the (meth)acrylic acid esters is 90 mass % or more of a total of all polymerization components of the (meth)acrylic acid ester resin, and
the pressure-induced phase transition particles have at least two glass transition temperatures, and a difference between the lowest glass transition temperature and the highest glass transition temperature among the glass transition temperatures of the pressure-induced phase transition particles is 30° C. or more.
2. The method for producing a printed material according to claim 1 , wherein the image area ratio of the color image is 10% or less.
3. The method for producing a printed material according to claim 1 , wherein the image area ratio of the color image is 2% or more.
4. The method for producing a printed material according to claim 1 , wherein the forming of the color image involves forming a pattern image of the color image on the peripheral edge portion of the recording medium.
5. The method for producing a printed material according to claim 4 , wherein the pattern image is a dotted pattern image.
6. The method for producing a printed material according to claim 4 , wherein the pattern image is a yellow image.
7. The method for producing a printed material according to claim 1 , wherein a mass ratio of styrene is within a range of 60 mass % to 95 mass % of a total of all polymerization components of the styrene resin in the pressure-induced phase transition particles.
8. The method for producing a printed material according to claim 1 , wherein a mass ratio between two (meth)acrylic acid esters contained at the largest mass ratio and the second largest mass ratio among the at least two (meth)acrylic acid esters contained as polymerization components of the (meth)acrylic acid ester resin in the pressure-induced phase transition particles is within a range of 80:20 to 20:80.
9. The method for producing a printed material according to claim 1 , wherein two (meth)acrylic acid esters contained at the largest mass ratio and the second largest mass ratio among the at least two (meth)acrylic acid esters contained as polymerization components of the (meth)acrylic acid ester resin in the pressure-induced phase transition particles are (meth)acrylic acid alkyl esters, and a difference in the number of carbon atoms between alkyl groups in the two (meth)acrylic acid alkyl esters is within a range of 1 to 4.
10. The method for producing a printed material according to claim 1 , wherein the vinyl monomer contained as a polymerization component of the styrene resin contains a (meth)acrylic acid ester.
11. The method for producing a printed material according to claim 1 , wherein the vinyl monomer contained as a polymerization component of the styrene resin is selected from n-butyl acrylate and 2-ethylhexyl acrylate.
12. The method for producing a printed material according to claim 1 , wherein the styrene resin and the (meth)acrylic acid ester resin contain the same (meth)acrylic acid ester as a polymerization component.
13. The method for producing a printed material according to claim 1 , wherein the (meth)acrylic acid ester resin contains 2-ethylhexyl acrylate and n-butyl acrylate as polymerization components.
14. The method for producing a printed material according to claim 1 , wherein an amount of the styrene resin contained in the pressure-induced phase transition particles is larger than an amount of the (meth)acrylic acid ester resin contained in the pressure-induced phase transition particles.
15. The method for producing a printed material according to claim 1 , wherein the pressure-induced phase transition particles have a sea phase containing the styrene resin and island phases containing the (meth)acrylic acid ester resin and being dispersed in the sea phase.
16. The method for producing a printed material according to claim 15 , wherein the island phases have an average size within a range of 200 nm to 500 nm.
17. The method for producing a printed material according to claim 1 , wherein the pressure-induced phase transition particles have a core containing the styrene resin and the (meth)acrylic acid ester resin, and a shell layer covering the core.
18. The method for producing a printed material according to claim 17 , wherein the shell layer contains the styrene resin.
19. The method for producing a printed material according to claim 1 , wherein a temperature at which the pressure-induced phase transition particles exhibit a viscosity of 10000 Pa·s at a pressure of 4 MPa is 90° C. or less.