Surfactant stabilization of hygroscopic species
Stable solid compositions employing a water conditioning agent, including hygroscopic species or non-hygroscopic species. In particular, solid compositions combining an ionic surfactant or an amphoteric surfactant with a water conditioning agent, preferably a polyacrylate water conditioning agent, are disclosed. The ionic surfactant or amphoteric surfactant beneficially stabilize the polymer and/or chelant water conditioning agent, preferably a polyacrylate water conditioning agent, to permit formulation into a solid composition and provide stability under harsh conditions, including humid environments. Applications of using the stable solid compositions are also disclosed.
1. A method for stabilizing a water conditioning agent into a stable solid composition comprising:
combining a water conditioning agent comprising from 22 wt-% to 26 wt-% of a chelant water conditioning agent comprising methylglycinediacetic acid (MGDA) and from 49 wt-% to 51 wt-% of a polycarboxylic acid polymer, copolymer and/or terpolymer (or salts thereof), and from 7.5 wt-% to 10 wt-% of a stabilizing surfactant comprising an amine oxide amphoteric surfactant to form a stable solid composition;
wherein the stable solid composition is pressed, cast or extruded;
wherein the stable solid composition does not comprise sodium carbonate; and
maintaining the stable solid composition, wherein the stable solid composition has less than 5% change in thickness and diameter when heated to a temperature of 40° C. for two weeks with 65% humidity.
2. The method of claim 1 , wherein the polycarboxylic acid polymer, copolymer and/or terpolymer (or salts thereof) is a polyacrylic acid copolymers or polyacrylate having a molecular weight between 1,000 and 100,000 g/mol.
3. The method of claim 1 , wherein the amine oxide amphoteric surfactant comprises a dodecyldimethylamine oxide, tridecyldimethylamine oxide, tetradecyldimethylamine oxide, pentadecyldimethylamine oxide, hexadecyldimethylamine oxide, heptadecyldimethylamine oxide, octadecyldimethylaine oxide, dodecyldipropylamine oxide, tetradecyldipropylamine oxide, hexadecyldipropylamine oxide, tetradecyldibutylamine oxide, octadecyldibutylamine oxide, bis(2-hydroxyethyl) dodecylamine oxide, bis(2-hydroxyethyl)-3-dodecoxy-1-hydroxypropylamine oxide, dimethyl-(2-hydroxydodecyl) amine oxide, 3,6,9-trioctadecyldimethylamine oxide, 3-dodecoxy-2-hydroxypropyldi-(2-hydroxyethyl) amine oxide, or combinations thereof.
4. The method of claim 1 , wherein the chelant water conditioning agent further comprises glutamic acid-diacetic acid (GLDA), iminiodisuccinic acid (IDA), hydroximinodisuccinic acid, or salt thereof.
5. The method of claim 1 , wherein the solid composition is phosphate free.