Polyurethane-containing tread rubber compositions and related methods
Disclosed herein are tread rubber compositions containing a specified polyurethane, tires containing a tread made from the rubber compositions, and related methods of improving the wet and dry traction of a tire tread by using the polyurethane-containing rubber compositions. The polyurethane includes a saturated hydroxy-functionalized polydiene segment as diol.
1. A tread rubber composition comprising:
a. 100 parts of at least one conjugated diene containing polymer or copolymer comprising at least one conjugated diene monomer;
b. 20 to 200 phr of at least one carbon black filler, at least one silica filler, or a combination thereof; and
c. 1 to 40 phr of at least one polyurethane including a saturated hydroxy-functionalized polydiene segment as diol, wherein the polyurethane has a Mw of 90,000 to 150,000 grams/mole; a Mn of 10,000 to 50,000 grams/mole; and a Mw/Mn of 2 to 10, with the Mw and Mn measured by GPC using a polystyrene standard, and a Tg of about −40 to about −20° C., and saturated refers to at least 90% of double bonds within the saturated hydroxy-functionalized polydiene segment having been saturated;
wherein the tread rubber composition contains no more than 15 phr of oil, and wherein the tread rubber composition contains less than 10% by weight of the at least one polyurethane based upon the total weight of the tread rubber composition.
2. The tread rubber composition of claim 1 , wherein the saturated hydroxy-functionalized polydiene segment has a number average of 1.6 to 2 terminal hydroxy groups per molecule.
3. The tread rubber composition of claim 1 , wherein the saturated hydroxy-functionalized polydiene segment is formed from at least one diene monomer selected from C 4 to C 10 dienes.
4. The tread rubber composition of claim 1 , wherein the at least one conjugated diene monomer of the at least one conjugated diene containing polymer or copolymer comprises a conjugated diene of C 4 to C 10 .
5. The tread rubber composition of claim 1 , wherein the saturated hydroxy-functionalized polydiene segment has a number average of 1.6 to 2 terminal hydroxy groups per molecule and a Mn of 500 to 20,000 grams/mole, wherein the Mn is measured by GPC using a polystyrene standard.
6. The tread rubber composition of claim 1 , wherein the polyurethane includes an aromatic diisocyanate selected from the group consisting of 4,4′-diphenylmethane diisocyanate, toluene diisocyanate, isophorone diisocyanate, hexamethylene diisocyanate, ethylene diisocyanate, paraphenyl diisocyanate, and combinations thereof.
7. The tread rubber composition of claim 1 , wherein the polyurethane includes an aromatic diisocyanate.
8. The tread rubber composition of claim 6 , wherein the saturated hydroxy-functionalized polydiene segment has a Mn of 500 to 20,000 grams/mole, wherein the Mn is measured by GPC using a polystyrene standard.
9. The tread rubber composition of claim 1 , wherein the polyurethane includes an aromatic diisocyanate selected from the group consisting of 4,4′-diphenylmethane diisocyanate, toluene diisocyanate, isophorone diisocyanate, hexamethylene diisocyanate, ethylene diisocyanate, paraphenyl diisocyanate, and combinations thereof.
10. The tread rubber composition of claim 5 , wherein the polyurethane further comprises at least one chain extender selected from the group consisting of C 2 -C 20 diols which are linear or branched, C 2 -C 20 amines, and combinations thereof.
11. The tread rubber composition of claim 5 , wherein the polyurethane contains 5 to 30% by weight of the saturated hydroxy-functionalized polydiene segment.
12. The tread rubber composition of claim 1 , wherein the polyurethane contains 5 to 30% by weight of the saturated hydroxy-functionalized polydiene segment.
13. The tread rubber composition of claim 1 , containing less than 5% by weight of the polyurethane, based upon the total weight of the tread rubber composition.
14. The tread rubber composition of claim 1 , wherein (b) includes at least 50 phr of silica filler and 0 phr of carbon black filler.
15. The tread rubber composition of claim 1 , wherein the polyurethane has a Tg of −34 to −26° C.
16. The tread rubber composition of claim 1 , wherein the polyurethane further comprises at least one chain extender selected from the group consisting of C 2 -C 20 diols that are linear or branched, C 2 -C 20 amines, and combinations thereof.
17. A tire containing a tread made from the tread rubber composition according to claim 1 .