Crumpled mesoporous MXene powders synthesized by acid-, base-, or salt-induced crumpling
The present disclosure describes a crumpled form of MXene materials, and methods of making and using these novel compositions.
1. A crumpled MXene or a composition comprising a crumpled MXene, wherein the crumpled MXene comprises a two dimensional crystalline transition metal carbide, nitride, or carbonitride arranged in a three-dimensional interpenetrating mesoporous structure.
2. The composition of claim 1 , wherein the crumpled MXene exhibits mesopores in a range of from 2 nm to 6 nm.
3. The composition of claim 1 , wherein the composition further comprises an alkali metal cation or alkyl ammonium cation incorporated into the crumpled MXene.
4. The composition of claim 1 , wherein the crumpled MXene contains lithium, sodium, or potassium ions within its three-dimensional interpenetrating mesoporous structure.
5. The composition of claim 1 , wherein the crumpled MXene is derived from a pH induced flocculation of a near pH neutral dispersion of delaminated MXene flakes.
6. The composition of claim 5 , wherein the pH induced flocculation results from the addition of an organic or inorganic mineral acid to the near pH neutral dispersion of the delaminated MXene flakes.
7. The composition of claim 6 , wherein the pH induced flocculation results from the addition of hydrochloric, nitric, or sulfuric acid to the near pH neutral dispersion of the delaminated MXene.
8. The composition of claim 5 , wherein the pH induced flocculation results from the addition of a hydroxide base to the near pH neutral dispersion of the delaminated MXene flakes.
9. The composition of claim 8 , wherein the pH induced flocculation results from the addition of LiOH, NaOH, KOH, or an alkyl substituted ammonium hydroxide to the near pH neutral dispersion of the delaminated MXene flakes.
10. The composition of claim 1 , wherein the crumpled MXene is derived from a salt induced flocculation of a near pH neutral dispersion of delaminated MXene flakes.
11. The composition of claim 1 , wherein the crumpled MXene contains an alkali metal, alkaline earth metal, alkyl ammonium, or transition metal cation within the MXene structure.
12. The composition of claim 1 , further comprising an organic polymer, wherein the organic polymer acts as a binder in which the crumpled MXene is distributed.
13. The composition of claim 12 further comprising an electrically conductive allotrope of carbon.
14. A composition of claim 1 , wherein the crumpled MXene contains within it at least one transition metal within its three-dimensional interpenetrating mesoporous structure.