Glass-coated aluminum nitride particles, method for producing same, and heat dissipating resin composition containing same

1. Glass-coated aluminum nitride particles comprising aluminum nitride particles, and

a glass phase covering at least a part of a surface of the aluminum nitride particles,

wherein

the glass phase is a composition comprising at least a glass component, and the composition comprising the glass component has a ratio of 0.2 parts by weight to 5.0 parts by weight with respect to 100 parts by weight of the aluminum nitride particles, and the composition comprising the glass component further comprises boron nitride particles, and the aluminum nitride particles have a volume cumulative d50 of 10 μm to 200 μm, and

the boron nitride particles have a ratio of 2.0 parts by weight or more and less than 5.0 parts by weight with respect to 100 parts by weight of the aluminum nitride particles.

2. The glass-coated aluminum nitride particles according to claim 1 , wherein an average aspect ratio of the aluminum nitride particles is 0.8 or more.

3. A method for producing the glass-coated aluminum nitride particles according to claim 1 , wherein

a volume cumulative d50 of a glass frit which is a raw material of the glass phase is 0.3 μm to 50 μm, comprising

a first step of forming a mixture by mixing the aluminum nitride particles, the glass frit, and boron nitride particles having a volume cumulative d50 of 0.3 μm to 30 μm,

a second step of obtaining coated particles by coating the glass frit onto the aluminum nitride particles by heat treating the mixture after the completion of the first step, at a temperature of the glass transition temperature of the glass frit or more, and 2000° C. or less, and

a third step of grinding the coated particles after the completion of the second step, to make particles with a volume cumulative d50 of 10 μm to 200 μm.

4. The method for producing glass-coated aluminum nitride particles according to claim 3 , wherein the second step is carried out under an atmosphere which does not include oxygen.

5. The method for producing glass-coated aluminum nitride particles according to claim 3 , wherein the heat treatment of the second step is carried out at 400° C. to 1400° C., in a range of 30 min to 3 hrs.

6. The method for producing glass-coated aluminum nitride particles according to claim 3 , further comprising, between the first step and the second step, a step of shaping by applying pressure to the mixture of the aluminum nitride particles, the glass frit, and the boron nitride particles.

7. The method for producing glass-coated aluminum nitride particles according to claim 6 , wherein the shaping step is carried out at a pressure of 10 MPa to 300 MPa.

8. A heat dissipating resin composition comprising the glass-coated aluminum nitride particles according to claim 1 .

9. Glass-coated aluminum nitride particles comprising aluminum nitride particles, and

a glass phase covering at least a part of a surface of the aluminum nitride particles,

wherein

the glass phase is a composition comprising at least a glass component, and the composition comprising the glass component has a ratio of 0.2 parts by weight to 5.0 parts by weight with respect to 100 parts by weight of the aluminum nitride particles, and the composition comprising the glass component further comprises boron nitride particles, and the aluminum nitride particles have a volume cumulative d50 of 10 μm to 200 μm, and

the glass component comprises SiO 2 , Al 2 O 3 , and B 2 O 3 .