Zinc-based plated steel sheet having excellent room temperature aging resistance and bake hardenability, and method for producing same
A zinc-based plated steel sheet having excellent room temperature aging resistance and bake hardenability includes a base steel sheet and a zinc-based plating layer formed on the surface of the base steel sheet, wherein the base steel sheet contains, in wt %, no more than 0.005% (excluding 0%) of C, 0.1-1.0% of Mn, no more than 0.3% (excluding 0%) of Si, 0.01-0.08% of P, no more than 0.01% of S, no more than 0.01% of N, 0.01-0.06% of sol.Al, 0.002-0.02% of Nb, and 0.001-0.004% (excluding 0.001%) of B, with the remainder comprising Fe and inevitable impurities, and CS in formula 1 below may satisfy the range of 0.0002-0.002%. In formula 1, [C] and [Nb] represent the contents (wt %) of C and Nb, respectively, in the base steel sheet. CS=[C]−(12/93)*[Nb] [Formula 1]
1 . A zinc-based plated steel sheet, the zinc-based plated steel sheet comprising:
a base steel sheet and a zinc-based plated layer formed on a surface of the base steel sheet;
a yield strength of 210 MPa or more; and
an elongation of 35% or more,
wherein the base steel sheet comprises, by weight percentage (wt %), carbon (C): 0.005% or less (excluding 0%), manganese (Mn): 0.1 to 1.0%, silicon (Si): 0.3% or less (excluding 0%), phosphorous (P): 0.01 to 0.08%, sulfur(S): 0.01% or less, nitrogen (N): 0.01% or less, soluble aluminum (sol.Al): 0.01 to 0.06%, niobium (Nb): 0.002 to 0.02%, boron (B): 0.001 to 0.004% (excluding 0.001%), and a balance of iron (Fe) and unavoidable impurities, and
R B of Relational Expression 2 below is 1.2 or more,
R B =R (BH)/ R (AI), Relational Expression 2:
where R(BH) of Relational Expression 2 denotes a concentration ratio of boron (B) present within 20 nm of a ferrite grain boundary in the base steel sheet in a grain direction during a heat treatment performed on the zinc-based plated steel sheet at a temperature of 170° C. for 20 minutes, and
R(AI) of Relational Expression 2 denotes a concentration ratio of boron (B) present within 20 nm of a ferrite grain boundary in the base steel sheet in the grain direction during a heat treatment performed on the zinc-based plated steel sheet at a temperature of 100° C. for 60 minutes.
2 . The zinc-based plated steel sheet of claim 1 , wherein the base steel sheet is a cold-rolled steel sheet.
3 . The zinc-based plated steel sheet of claim 1 , wherein a microstructure of the base steel sheet is a ferrite single-phase structure, and
wherein the ferrite single-phase structure includes grains having an average diameter of 8 μm or less, and the grains account for 70% or more of area ratio in a cross section of the base steel sheet.
4 . The zinc-based plated steel sheet of claim 1 , wherein a lower-bake hardening (L-BH) value of the zinc-based plated steel sheet is 30 MPa or more, and an aging index (AI) of the zinc-based plated steel sheet is 0.2% or less.
5 . A zinc-based plated steel sheet, the zinc-based plated steel sheet comprising:
a base steel sheet and a zinc-based plated layer formed on a surface of the base steel sheet;
a yield strength of 210 MPa or more; and
an elongation of 35% or more,
wherein the base steel sheet comprises, by weight percentage (wt %), carbon (C): 0.005% or less (excluding 0%), manganese (Mn): 0.1 to 1.0%, silicon (Si): 0.3% or less (excluding 0%), phosphorous (P): 0.01 to 0.08%, sulfur(S): 0.01% or less, nitrogen (N): 0.01% or less, soluble aluminum (sol.Al): 0.01 to 0.06%, niobium (Nb): 0.002 to 0.02%, boron (B): 0.001 to 0.004% (excluding 0.001%), and a balance of iron (Fe) and unavoidable impurities, and
C S of Relational Expression 1 below satisfies a range of 0.0002% to 0.002%, and
R B of Relational Expression 2 below is 1.2 or more,
C S =[C]−(12/93)*[Nb] Relational Expression 1:
where [C] and [Nb] of Relational Expression 1 refer to contents (wt %) of C and Nb of the base steel sheet, respectively, and
R B =R (BH)/ R (AI), Relational Expression 2:
where R(BH) of Relational Expression 2 denotes a concentration ratio of boron (B) present within 20 nm of a ferrite grain boundary in the base steel sheet in a grain direction during a heat treatment performed on the zinc-based plated steel sheet at a temperature of 170° C. for 20 minutes, and
R(AI) of Relational Expression 2 denotes a concentration ratio of boron (B) present within 20 nm of a ferrite grain boundary in the base steel sheet in the grain direction during a heat treatment performed on the zinc-based plated steel sheet at a temperature of 100° C. for 60 minutes.
6 . The zinc-based plated steel sheet of claim 5 , wherein the base steel sheet is a cold-rolled steel sheet.
7 . The zinc-based plated steel sheet of claim 5 , wherein a microstructure of the base steel sheet is a ferrite single-phase structure, and
wherein the ferrite single-phase structure includes grains having an average diameter of 8 μm or less, and the grains account for 70% or more of area ratio in a cross section of the base steel sheet.
8 . The zinc-based plated steel sheet of claim 5 , wherein a lower-bake hardening (L-BH) value of the zinc-based plated steel sheet is 30 MPa or more, and an aging index (AI) of the zinc-based plated steel sheet is 0.2% or less.
9 . A method for manufacturing a zinc-based plated steel sheet, the method comprising:
reheating a slab to a temperature within a range of 1160° C. to 1250° C., the slab comprising, by weight percentage (wt %), carbon (C): 0.005% or less (excluding 0%), manganese (Mn): 0.1 to 1.0%, silicon (Si): 0.3% or less (excluding 0%), phosphorous (P): 0.01 to 0.08%, sulfur(S): 0.01% or less, nitrogen (N): 0.01% or less, soluble aluminum (sol.Al): 0.01 to 0.06%, niobium (Nb): 0.002 to 0.02%, boron (B): 0.001 to 0.004% (excluding 0.001%), a balance of iron (Fe), and unavoidable impurities;
hot rolling the reheated slab to a temperature within a range of 850° C. to 1150° C. to provide a hot-rolled steel sheet;
cooling the hot-rolled steel sheet at an average cooling rate of 10° C./sec to 70° C./sec and coiling the cooled hot-rolled steel sheet to a temperature within a range of 500° C. to 750° C.;
cold rolling the coiled hot-rolled steel sheet at a reduction ratio of 70% to 90% to provide a cold-rolled steel sheet;
heating the cold-rolled steel sheet in a furnace atmosphere with a hydrogen concentration of 3% to 30% to a temperature within a range of 750° C. to 860° C. to be continuously annealed;
cooling the continuously annealed cold-rolled steel sheet; and
providing the cold-rolled steel sheet as a base steel sheet and dipping the cold-rolled steel sheet into a hot-dip zinc-based plating bath to manufacture a zinc-based plated steel sheet, wherein the cold rolling is performed by sequential reduction using a plurality of rolling rolls and a reduction ratio of an initial rolling roll, among the plurality of rolling rolls, is 20% to 40%,
in the base steel,
C S of Relational Expression 1 below satisfies a range of 0.0002% to 0.002%, and
R B of Relational Expression 2 below is 1.2 or more,
C S =[C]−(12/93)*[Nb] Relational Expression 1:
where [C] and [Nb] of Relational Expression 1 refer to contents (wt %) of C and Nb of the base steel sheet, respectively, and
R B =R (BH)/ R (AI), Relational Expression 2:
where R(BH) of Relational Expression 2 denotes a concentration ratio of boron (B) present within 20 nm of a ferrite grain boundary in the base steel sheet in a grain direction during a heat treatment performed on the zinc-based plated steel sheet at a temperature of 170° C. for 20 minutes, and
R(AI) of Relational Expression 2 denotes a concentration ratio of boron (B) present within 20 nm of a ferrite grain boundary in the base steel sheet in the grain direction during a heat treatment performed on the zinc-based plated steel sheet at a temperature of 100° C. for 60 minutes.
10 . The method of claim 9 , wherein the annealed cold-rolled steel sheet is primarily cooled to a temperature within a range of 630° C. to 670° C. at an average cooling rate of 2° C./sec to 10° C./sec, and
the primarily cooled cold-rolled steel sheet is secondarily cooled to a temperature within a range of 440° C. to 480° C. at an average cooling rate of 3° C./sec to 20° C./sec.
11 . The method of claim 9 , wherein the cold-rolled steel sheet is dipped in a hot-dip zinc-based plating bath of 440° C. to 480° C.
12 . The method of claim 9 , wherein the zinc-based plated steel sheet is temper-rolled at a reduction ratio of 0.3% to 1.6%.