Binder including copolymer of styrene, (meth)acrylate, and surfactant having unsaturated bond, slurry having the same, nonaqueous battery electrode using the same, and nonaqueous battery using the same
A binder for a nonaqueous battery electrode, the nonaqueous battery electrode using the binder for the nonaqueous battery electrode, and a nonaqueous battery. The binder for a nonaqueous battery electrode contains a copolymer (P) of an ethylenically unsaturated monomer (A) essentially containing a styrene-based monomer (a1) and a (meth)acrylate ester (a2), and a surfactant (B1) having an ethylenically unsaturated bond, wherein the total amount of structure units derived from the surfactant (B1) having the ethylenically unsaturated bond in the copolymer (P) and the surfactant (B2) not contained in the copolymer (P) is 0.10 to 1.00 parts by mass based on 100 parts by mass of the copolymer (P). Also disclosed is a method for producing the binder.
1. A slurry for a nonaqueous battery electrode, comprising:
an active material;
a binder for the nonaqueous battery electrode; and
an aqueous medium,
wherein the slurry for the nonaqueous battery electrode is for forming a negative electrode, and the active material is a negative electrode active material comprising at least one selected from the group consisting of conductive polymer, carbon material, lithium titanate, and silicon, and
the binder for the nonaqueous battery electrode comprises:
a copolymer (P) of
an ethylenically unsaturated monomer (A) comprising a styrene-based monomer (a1) and a (meth)acrylate (a2), and
a surfactant (B1) having an ethylenically unsaturated bond; and
a surfactant (B2) not contained in the copolymer (P),
wherein a total amount of
a structural unit derived from the surfactant (B1) having the ethylenically unsaturated bond in the copolymer (P), and
the surfactant (B2) not contained in the copolymer (P)
is 0.10 parts by mass or more and less than 0.30 parts by mass with respect to 100 parts by mass of the copolymer (P).
2. The slurry for the nonaqueous battery electrode according to claim 1 ,
wherein in the ethylenically unsaturated monomer (A), the total amount of the styrene-based monomer (a1) and the (meth)acrylate (a2) is 70 to 100% by mass.
3. The slurry for a nonaqueous battery electrode according to claim 1 ,
wherein in the ethylenically unsaturated monomer (A), the total amount of the styrene-based monomer (a1) is 15.0 to 70.0% by mass.
4. The slurry for nonaqueous battery electrodes according to claim 1 ,
wherein the styrene-based monomer (a1) is at least one selected from the group consisted of styrene, chlorostyrene, vinyltoluene, t-butylstyrene, vinylbenzoic acid, methyl vinylbenzoate, vinylnaphthalene, chloromethylstyrene, hydroxymethylstyrene, p-styrenesulfonic acid, and sodium p-styrenesulfonate.
5. The slurry for nonaqueous battery electrodes according to claim 1 ,
wherein in the ethylenically unsaturated monomer (A), the total amount of the (meth)acrylate (a2) is 30.0 to 85.0% by mass.
6. The slurry for a nonaqueous battery electrode according to claim 1 , further comprising:
an ethylenically unsaturated carboxylic acid (a3) having one ethylenically unsaturated bond in the molecule.
7. The slurry for a nonaqueous battery electrode according to claim 1 ,
wherein the copolymer (P) is obtained by emulsion polymerization of the ethylenically unsaturated monomer (A) and the surfactant (B1)
in the presence of the surfactant (B1) and the surfactant (B2).
8. The slurry for a nonaqueous battery electrode according to claim 1 ,
wherein the binder has a glass transition temperature of 30° C. or less.
9. A nonaqueous battery negative electrode, comprising:
an electrode current collector, and
an active material layer formed by drying the slurry for the nonaqueous battery electrodes according to claim 1 on at least one surface of the electrode current collector.
10. A nonaqueous battery comprising the nonaqueous negative battery electrode according to claim 9 .