Polyarylene sulfide resin composition having excellent mechanical and corrosion properties
A polyarylene sulfide resin composition contains a polyarylene sulfide resin, a transition metal particle, a fibrous inorganic filler, and an inorganic nucleating agent, and a molded article made from the resin composition. The resin composition has excellent mechanical, corrosion, and haze properties, and heat resistance. The resin composition prevents corrosion of a mold and deterioration in the durability of a manufactured product upon injection by effectively removing halogen-based impurities, and also has excellent mechanical, corrosion, and haze properties, and heat resistance. A molded article manufactured from the resin composition satisfies the standards required for components of a vehicle and an electric/electronic device.
1. A resin composition, which comprises
a polyarylene sulfide resin in an amount of 40 to 65% by weight,
a transition metal particle in an amount of 0.05 to 5.0% by weight,
a fibrous inorganic filler in an amount of 30 to 55% by weight, and
an inorganic nucleating agent in an amount of 0.1 to 2% by weight, each based on a total amount of the resin composition.
2. The resin composition of claim 1 , wherein the polyarylene sulfide resin has a melt viscosity of 300 to 10,000 poises at 300° C. and a number average molecular weight of 7,000 to 30,000 g/mole.
3. The resin composition of claim 1 , wherein the transition metal particle has an average diameter of 0.1 to 10 μm and is spherical-shaped and/or plate-shaped.
4. The resin composition of claim 1 , wherein the transition metal particle comprises one or more transition metal selected from the group consisting of copper, nickel, titanium, zinc, chromium, and gold.
5. The resin composition of claim 1 , wherein the fibrous inorganic filler has an average diameter of 6 to 15 μm and an average length of 1 to 5 mm, and is surface-treated with a silane selected from the group consisting of amino-based silane, epoxy-based silane, urethane-based silane, and combinations thereof.
6. The resin composition of claim 1 , wherein the fibrous inorganic filler is an alumino-borosilicate glass fiber.
7. The resin composition of claim 1 , wherein the inorganic nucleating agent comprises one or more selected from the group consisting of a borate, boron sulfide (B 2 S 3 ), boron chloride (BCl 3 ), boron acid (H 3 O 3 ), colemanite, zinc borate, boron carbide (B 4 C), boron nitride (BN), and boron oxide (B 2 O 3 ).
8. The resin composition of claim 1 , which further comprises one or more compatibilizer selected from the group consisting of an epoxy-based silane, a mercapto-based silane, and an amino-based silane.
9. The resin composition of claim 1 , which further comprises one or more additive selected from the group consisting of a heat stabilizer, a lubricant, an antistatic agent, a slip agent, and a pigment.
10. The resin composition of claim 1 , wherein the transition metal particle has an average diameter of 0.1 to 10 μm and is amorphous.
11. A molded article produced by molding the resin composition of claim 1 .
12. The molded article of claim 11 , which is an automobile part, an electric part, or an electronic part.
13. The molded article of claim 11 , which is a thin-layer molded article or an injection molded article.
14. A molded article produced by molding the resin composition of claim 2 .
15. A molded article produced by molding the resin composition of claim 3 .
16. A molded article produced by molding the resin composition of claim 5 .
17. A molded article produced by molding the resin composition of claim 7 .
18. A molded article produced by molding the resin composition of claim 8 .
19. A molded article produced by molding the resin composition of claim 10 .