Conversion of ethane to ethylene
View Patent ↗Methods of converting ethane to ethylene at relatively low temperatures are described. Ir02-based catalysts are used in the conversion. Methods of converting a base gas to a first gas by exposing the base gas to an IrO2-based catalyst and forming the first gas are described. The base gas can be an alkane. The first gas can include an alkene, an alkyne, an alcohol, an aldehyde, or combinations thereof.
1. A method of converting a base gas to a first gas, comprising:
exposing the base gas to an IrO 2 -based catalyst and forming the first gas, wherein the base gas is an alkane, wherein the first gas comprises an alkene, an alkyne, an alcohol, an aldehyde, or a combination thereof, and wherein the IrO 2 -based catalyst comprises;
IrO 2 ; and
prehydrogenating the IrO 2 -based catalyst prior to exposing the alkane to the IrO 2 -based catalyst, wherein prehydrogenating comprises adsorbing hydrogen onto a surface of the IrO 2 -based catalyst to convert at least a portion of oxygen to OH.
2. The method of claim 1 , wherein the alkane is a C1 to C5 alkane.
3. The method of claim 1 , wherein the first gas comprises a C1 to C5 alkene, a C1 to C5 alkyne, a C1 to C5 alcohol, a C1 to C5 aldehyde, or a combination thereof.
4. The method of claim 1 , wherein the IrO 2 -based catalyst is IrO 2 (110).
5. The method of claim 1 , wherein exposing comprises exposing the alkane to the IrO 2 -based catalyst at a temperature of about 200 to 400 K.
6. The method of claim 1 , wherein the IrO 2 -based catalyst comprises IrO 2 deposited onto a support.
7. The method of claim 6 , wherein the support is an oxide support selected from SiO 2 , Al 2 O 3 , TiO 2 , MgO, CaO, CeO 2 , zeolites, and a combination thereof.
8. The method of claim 6 , wherein the support is a non-oxide support.
9. The method of claim 1 , wherein the IrO 2 -based catalyst is IrO 2 (110), wherein the base gas is ethane, and the first gas is ethylene.
10. The method of claim 1 , wherein the IrO 2 based catalyst is IrO 2 (110), wherein the base gas is methane and the first gas comprises ethylene, methanol, formaldehyde, or a combination thereof.
11. A method of converting a base gas to a first gas, comprising:
exposing the base gas to an IrO 2 -based catalyst and forming the first gas, wherein the base gas is ethane, the first gas is ethylene, and the IrO 2 -based catalyst comprises IrO 2 ; and
prehydrogenating the IrO 2 -based catalyst prior to exposing the alkane to the IrO 2 -based catalyst, wherein prehydrogenating comprises adsorbing hydrogen onto a surface of the IrO 2 -based catalyst to convert at least a portion of oxygen to OH.
12. The method of claim 11 , wherein the IrO 2 -based catalyst is IrO 2 (110).
13. The method of claim 11 , wherein exposing comprises exposing the ethane to the IrO 2 -based catalyst at a temperature of about 200 to 400 K.
14. The method of claim 11 , wherein the IrO 2 -based catalyst comprises IrO 2 deposited onto a support.
15. The method of claim 14 , wherein the support is an oxide support selected from SiO 2 , Al 2 O 3 , TiO 2 , MgO, CaO, CeO 2 , zeolites, and a combination thereof.
16. The method of claim 15 , wherein the support is a non-oxide support.