Oriented apatite type oxide ion conductor and method for producing same
An oriented apatite-type oxide ion conductor includes a composite oxide expressed as A 9.33+x [T 6.00−y M y ]O 26.0+z , where A represents one or two or more elements selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Be, Mg, Ca, Sr, and Ba, T represents an element including Si or Ge or both, and M represents one or two or more elements selected from the group consisting of B, Ge, Zn, Sn, W, and Mo, and where x is from −1.00 to 1.00, y is from 0.40 to less than 1.00, and z is from −3.00 to 2.00.
1. An oriented apatite-type oxide ion conductor comprising a composite oxide expressed as A 9.33+x [T 6.00−y M y ]O 26.0+z , where A represents one or two or more elements selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Be, Mg, Ca, Sr, and Ba, T represents an element including Si or Ge or both, and M represents one or two or more elements selected from the group consisting of B, Ge, Zn, Sn, W, and Mo, and where x is from −1.00 to 1.00, y is from 0.40 to less than 1.00, and z is from −3.00 to 2.00.
2. The oriented apatite-type oxide ion conductor as set forth in claim 1 , which has a degree of orientation of 0.60 or greater as measured according to the Lotgering method.
3. An electrode assembly that has a configuration in which electrodes are stacked on two surfaces of the oriented apatite-type oxide ion conductor as set forth in claim 1 .
4. A method for producing an oriented apatite-type oxide ion conductor, comprising:
a step of converting a precursor expressed as A 2.00+x TO 5.00+z , where A represents one or two or more elements selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Be, Mg, Ca, Sr, and Ba, T represents an element including Si or Ge or both, x is from −1.00 to 1.00, and z is from −2.00 to 2.00, into an oriented apatite-type crystal structure by heating the precursor in a gas phase containing an element M, where M represents one or two or more elements selected from the group consisting of B, Ge, Zn, Sn, W, and Mo, and thereby reacting the element M with the precursor; and
an annealing step.
5. An electrode assembly that has a configuration in which electrodes are stacked on two surfaces of the oriented apatite-type oxide ion conductor as set forth in claim 2 .