FCC catalyst with enhanced mesoporosity, its preparation and use
Process for the preparation of a catalyst and a catalyst comprising enhanced mesoporosity is provided herein. Thus, in one embodiment, provided is a particulate FCC catalyst comprising 2 to 50 wt % of one or more ultra stabilized high SiO2/Al2O3 ratio large pore faujasite zeolite or a rare earth containing USY, 0 to 50 wt % of one or more rare-earth exchanged large pore faujasite zeolite, 0 to 30 wt % of small to medium pore size zeolites, 5 to 45 wt % quasi-crystalline boehmite 0 to 35 wt % microcrystalline boehmite, 0 to 25 wt % of a first silica, 2 to 30 wt % of a second silica, 0.1 to 10 wt % one or more rare earth components showiomg enhanced mesoporosity in the range of 6-40 nm, the numbering of the silica corresponding to their orders of introduction in the preparation process.
1. An FCC catalyst composition comprising a first zeolite of about 2 to about 50 wt % selected from the group of one or more ultra stabilized or rare earth exchanged ultra stabilized Y with a SiO2/Al2O3 ratio greater than 6.5, optionally a second zeolite of 0 to about 50 wt % of one or more rare-earth exchanged Y zeolite, optionally 0 to 30 wt % of small to medium pore zeolite, about 5 to about 45 wt % alumina from a quasicrystalline boehmite source, about 0 to about 35 wt % alumina from a microcrystalline boehmite source, a first silica source of about 0 to about 20 wt %, a second silica source of about 2 to about 30 wt %, about 0.1 to about 10 wt % one or more rare earth components as oxide and the balance clay, wherein the FCC catalyst has about 20 to about 30% of the total pore volume contributed by pores at a diameter of about 2.0 to about 6 nm and about 55 to about 70% of the pore volume of pores at a diameter of about 6 to 40 nm.
2. The FCC Catalyst of claim 1 wherein the first zeolite is one or more ultra stabilized Y zeolites.
3. The FCC Catalyst of claim 1 wherein the first zeolite is one or more rare earth exchanged ultra stabilized Y zeolites.
4. The FCC Catalyst of claim 1 wherein the one or more rare earth components comprise lanthanum, yttrium, cerium or mixtures thereof.
5. The FCC Catalyst of claim 1 wherein the one or more rare earth components comprise lanthanum.
6. The FCC Catalyst of claim 1 wherein the one or more rare earth components are added to the catalyst as hydroxide, chloride, oxide, nitrate, sulfate, oxychlorides, acetates, or carbonates.
7. The FCC Catalyst of claim 6 wherein the one or more rare earth components comprise lanthanum nitrate.
8. The FCC Catalyst of claim 1 wherein the medium pore zeolite comprises ZSM-5, ZSM-11, ZSM-22, Ferrierite, or mixtures thereof in the amount of greater than 0 to 30 wt %.
9. The FCC Catalyst of claim 1 wherein the first silica source comprises sodium stabilized colloidal silica in the amount of greater than about 0 to about 20 wt %.
10. The FCC Catalyst of claim 1 wherein the second silica source comprises acidic colloidal silica or ammonia stabilized colloidal silica or low-sodium stabilized colloidal silica or polysilicic acid, or mixtures thereof.