IP Library Granted Patent US 11,220,471
Granted Patent B2
US 11,220,471 · App. 16/962,943 · Granted Jan 11, 2022

Method for producing tetrafluoromethane

Inventors: Yohsuke Fukuchi (Tokyo, JP); Tomokazu Sugawara (Tokyo, JP); Shinya Oguro (Tokyo, JP); Hiroshi Kobayashi (Tokyo, JP)
Assignee: SHOWA DENKO K.K.
C07C17/367C07C17/204C07C17/361C07C19/08
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Quick Facts
Patent No.
US 11,220,471
App. No.
16/962,943
Granted
Jan 11, 2022
Kind
B2
Abstract

Provided is a method for producing tetrafluoromethane, and the method is unlikely to damage a reaction apparatus and can produce tetrafluoromethane safely, inexpensively, and stably. To a raw material liquid ( 1 ) containing a reaction inducer and a fluorinated hydrocarbon represented by chemical formula C p H q Cl r F s (in the chemical formula, p is an integer of 3 or more and 18 or less, q is an integer of 0 or more and 3 or less, r is an integer of 0 or more and 9 or less, and s is an integer of 5 or more and 30 or less) and having no carbon-carbon unsaturated bond, fluorine gas is introduced to give tetrafluoromethane. The reaction inducer is a hydrocarbon polymer solid at normal temperature and pressure and is reacted with fluorine gas to induce a reaction of forming tetrafluoromethane from the fluorinated hydrocarbon and the fluorine gas.

Claims (8)

1. A method for producing tetrafluoromethane, the method comprising:

introducing fluorine gas to a raw material liquid containing a reaction inducer and a fluorinated hydrocarbon represented by chemical formula C p H q Cl r F s (in the chemical formula, p is an integer of 3 or more and 18 or less, q is an integer of 0 or more and 3 or less, r is an integer of 0 or more and 9 or less, and s is an integer of 5 or more and 30 or less) and having no carbon-carbon unsaturated bond,

wherein the reaction inducer is a hydrocarbon polymer solid at normal temperature and pressure and is reacted with the fluorine gas to induce a reaction of forming tetrafluoromethane from the fluorinated hydrocarbon and the fluorine gas.

2. The method for producing tetrafluoromethane according to claim 1 , wherein the reaction inducer is contained at a content of more than 0% by mass and not more than 1% by mass where a total content of the fluorinated hydrocarbon and the reaction inducer contained in the raw material liquid is 100% by mass.

3. The method for producing tetrafluoromethane according to claim 2 , wherein the hydrocarbon polymer is at least one polymer selected from polyethylene, polypropylene, polystyrene, and paraffin.

4. The method for producing tetrafluoromethane according to claim 1 , wherein the fluorinated hydrocarbon is at least one fluorine-containing substance selected from a perfluorocarbon, a fluorohydrocarbon, a chlorofluorocarbon, a chlorofluorohydrocarbon, and a chlorotrifluoroethylene polymer.

5. The method for producing tetrafluoromethane according to claim 2 , wherein the fluorinated hydrocarbon is at least one fluorine-containing substance selected from a perfluorocarbon, a fluorohydrocarbon, a chlorofluorocarbon, a chlorofluorohydrocarbon, and a chlorotrifluoroethylene polymer.

6. The method for producing tetrafluoromethane according to claim 3 , wherein the fluorinated hydrocarbon is at least one fluorine-containing substance selected from a perfluorocarbon, a fluorohydrocarbon, a chlorofluorocarbon, a chlorofluorohydrocarbon, and a chlorotrifluoroethylene polymer.

Assignments (3)
CHANGE OF ADDRESS Recorded Feb 14, 2024
From: RESONAC CORPORATION
To: RESONAC CORPORATION
Reel/Frame 066599/0037 →
CHANGE OF NAME Recorded Jun 23, 2023
From: SHOWA DENKO K.K.
To: RESONAC CORPORATION
Reel/Frame 064082/0513 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 17, 2020
From: FUKUCHI, YOHSUKE; SUGAWARA, TOMOKAZU; OGURO, SHINYA; KOBAYASHI, HIROSHI
To: SHOWA DENKO K.K.
Reel/Frame 053241/0624 →