Process for preparing graphene
A process for preparing a product comprising one or more graphene layers, the process comprising: producing hydrodynamic cavitation in a liquid medium comprising a diaromatic component to synthesise the one or more graphene layers from the diaromatic component.
1. A process for preparing a product comprising one or more graphene layers, the process comprising: producing hydrodynamic cavitation in a liquid medium comprising a diaromatic component comprising one or more optionally substituted fused or linked diaromatic hydrocarbons to synthesize the one or more graphene layers from the diaromatic component.
2. The process of claim 1 , wherein the hydrodynamic cavitation is produced by flowing a feed of the liquid medium through a constriction.
3. The process of claim 2 , wherein the constriction has a maximum width of less than 1 mm.
4. The process of claim 2 , comprising flowing a feed of liquid medium into a conduit having a principal axis, wherein the conduit is arranged to direct the liquid medium against an impact head having a face perpendicular or predominantly perpendicular to said principal axis; the impact head and the conduit being arranged so that said constriction results between an end of the conduit proximate to the impact head and the impact head.
5. The process of claim 2 , wherein the feed of liquid medium is pressurised to a pressure of at least 300 bar or a pressure drop from the feed to the end of the constriction is at least 300 bar.
6. The process of claim 1 , wherein the liquid medium is kept at a temperature within a range of plus/minus 5° C.
7. The process of claim 1 , wherein the liquid medium is recycled and cavitation is repeatedly produced therein.
8. The process of claim 1 , wherein the one or more graphene layers comprise one or more heteroatom impurities.
9. The process of claim 1 , wherein the one or more graphene layers are oxidized.
10. The process of claim 1 , wherein the one or more graphene layers are functionalized.
11. The process of claim 1 , wherein the product comprises a substrate-borne graphene material formed by synthesizing the one or more graphene layers on substrate particles.
12. The process of claim 1 , wherein the diaromatic component is a diaromatic hydrocarbon component consisting of one or more optionally substituted fused or linked diaromatic hydrocarbons.
13. The process of claim 1 , wherein the diaromatic component comprises one or more diaromatic hydrocarbon compounds of Formula A or Formula B, optionally substituted with one or more moieties at one or more of the numbered positions:
14. The process of claim 13 , wherein the diaromatic component comprises one or more diaromatic hydrocarbon compounds of Formula A or Formula B substituted with one or more moieties selected from methyl, ethyl, and halides.
15. The process of claim 1 , wherein the diaromatic component comprises 1-methylnaphthalene.
16. The process of claim 1 , wherein the liquid medium comprises a stabilizing component for stabilizing a dispersion of graphene nanomaterial.
17. The process of claim 16 , wherein the stabilizing component comprises N-Methyl-2-pyrrolidone (NMP).
18. A process for preparing a product comprising one or more graphene layers, the process comprising: producing hydrodynamic cavitation in a liquid medium comprising a diaromatic component comprising methylnaphthalene, and optionally naphthalene to synthesize the one or more graphene layers from the diaromatic component, wherein the hydrodynamic cavitation is produced by flowing a feed of the liquid medium pressurized to a pressure of at least 300 bar through a constriction.