Thermal conduction sheet and heat dissipating device including thermal conduction sheet
Provided is a thermal conduction sheet, including graphite particles (A) of at least one kind selected from the group consisting of flake-shaped particles, ellipsoidal particles, and rod-shaped particles, in which: when the graphite particles (A) are flake-shaped particles, a planar direction of the graphite particles (A) is oriented in a thickness direction of the thermal conduction sheet, when the graphite particles (A) are ellipsoidal particles, a major axis direction of the graphite particles (A) is oriented in the thickness direction of the thermal conduction sheet, when the graphite particles (A) are rod-like particles, a longitudinal direction of the graphite particles (A) is oriented in the thickness direction of the thermal conduction sheet, the thermal conduction sheet has an elastic modulus of 1.4 MPa or less under a compression stress of 0.1 MPa at 150° C., and the thermal conduction sheet has a tack strength of 5.0 N·mm or higher at 25° C.
1. A thermal conduction sheet, comprising graphite particles (A) of at least one kind selected from the group consisting of flake-shaped particles, ellipsoidal particles, and rod-shaped particles, wherein:
when the graphite particles (A) are flake-shaped particles, a planar direction of the graphite particles (A) is oriented in a thickness direction of the thermal conduction sheet,
when the graphite particles (A) are ellipsoidal particles, a major axis direction of the graphite particles (A) is oriented in the thickness direction of the thermal conduction sheet,
when the graphite particles (A) are rod-like particles, a longitudinal direction of the graphite particles (A) is oriented in the thickness direction of the thermal conduction sheet,
the thermal conduction sheet has an elastic modulus of 1.4 MPa or less under a compression stress of 0.1 MPa at 150° C.,
the thermal conduction sheet has a tack strength of 5.0 N·mm or higher at 25° C., and
the thermal conduction sheet is obtained by kneading a composition containing the graphite particles (A) and forming the kneaded composition into a sheet, the composition being kneadable at 150° C.
2. The thermal conduction sheet according to claim 1 , further comprising a component (B) that is a liquid at 25° C.
3. The thermal conduction sheet according to claim 2 , wherein the component (B) that is a liquid at 25° C. comprises a polybutene.
4. The thermal conduction sheet according to claim 1 , further comprising an acrylate-based polymer (C).
5. The thermal conduction sheet according to claim 4 , wherein the acrylate-based polymer (C) has a glass transition temperature of 20° C. or lower.
6. The thermal conduction sheet according to claim 1 , further comprising an ethylene-α-olefin copolymer (D).
7. The thermal conduction sheet according to claim 1 , further comprising a hot-melt agent (E).
8. The thermal conduction sheet according to claim 1 , further comprising an antioxidant (F).
9. The thermal conduction sheet according to claim 1 , wherein the graphite particles (A) comprise flake-shaped particles that comprise expandable graphite particles.
10. The thermal conduction sheet according to claim 1 , wherein a content of the graphite particles (A) is from 15% by volume to 50% by volume.
11. A heat dissipating device, comprising:
a heat generating element;
a heat dissipating element; and
the thermal conduction sheet according to claim 1 , which is arranged between the heat generating element and the heat dissipating element.
12. The thermal conduction sheet according to claim 1 , wherein the sheet comprises a mixture containing a resin and the graphite particles (A).
13. The thermal conduction sheet according to claim 12 , wherein an amount of the graphite particles (A) is 10% by volume or more with respect to the resin.
14. The thermal conduction sheet according to claim 1 , wherein the graphite particles (A) comprise ellipsoidal particles.
15. The thermal conduction sheet according to claim 1 , wherein the graphite particles (A) comprise rod-shaped particles.
16. The thermal conduction sheet according to claim 2 , further comprising an acrylate-based polymer (C).
17. The thermal conduction sheet according to claim 16 , wherein the acrylate-based polymer (C) has a glass transition temperature of 20° C. or lower.
18. The thermal conduction sheet according to claim 16 , further comprising an ethylene-α-olefin copolymer (D).
19. The thermal conduction sheet according to claim 18 , further comprising a hot-melt agent (E).
20. The thermal conduction sheet according to claim 19 , further comprising an antioxidant (F).