Method for producing carbonaceous material for negative electrode of non-aqueous electrolyte secondary battery and production apparatus thereof

1. A method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery, the method comprising: a heat treatment step and an exhaust gas treatment step, the heat treatment step comprising:

continuously feeding a carbon precursor containing an alkali metal element and/or an alkali metal compound from a feeding unit of a rotary kiln including the feeding unit, a discharge unit, a furnace reactor tube, and an exhaust unit provided inside the furnace reactor tube;

introducing a non-oxidizing Ras from a Ras injection unit provided on the discharge unit side in a direction from the discharge unit side to the feeding unit side;

heating the carbon precursor in a temperature range of 10000 C to 15000 C in a non-oxidizing gas atmosphere to produce a carbonaceous material, and discharging the carbonaceous material continuously from the discharge unit, the discharging including suctioning, into the exhaust unit, a non-oxidizing exhaust gas that contains evolved gas containing alkali metal vaporized by the heating and contains a flying carbonaceous matter flying from the carbon precursor and the carbonaceous material;

the exhaust gas treatment step comprising:

blowing the exhaust gas into a cooling can filled with water or an aqueous solution to bring the exhaust gas into direct contact with the water or aqueous solution so that the evolved gas in the exhaust gas is cooled and absorbed, and at the same time, the flying carbonaceous matter is collected in the water or aqueous solution.

2. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery according to claim 1 , wherein the heat treatment step includes providing the suctioning the exhaust gas into a suction port of the exhaust unit that is provided to face the discharge unit side and provided on a side where the carbonaceous material is discharged, feeding side of the carbon precursor to suction the exhaust gas.

3. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery according to claim 2 , wherein in the heating step, a suction port of the furnace reactor tube has a temperature of 600 C or more.

4. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery according to claim 2 , wherein the exhaust gas treatment step further includes a recovery step of filtering the water or aqueous solution in which the exhaust gas has been absorbed and recovering the flying carbonaceous matter in the aqueous solution.

5. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery according to claim 2 , wherein in the heat treatment step, the carbon precursor is fed so that an areal weight is 15 kg/m2 or less.

6. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery according to claim 1 , wherein the exhaust gas treatment step further includes a recovery step of filtering the water or aqueous solution in which the exhaust gas has been absorbed and recovering the flying carbonaceous matter in the aqueous solution.

7. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery according to claim 1 , wherein in the heat treatment step, the carbon precursor is fed so that an areal weight is 15 kg/m2 or less.

8. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery according to claim 1 , wherein the heat treatment step further includes introducing the non-oxidizing gas in a direction from a carbonaceous material feeding side to a carbonaceous material discharging side.

9. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery according to claim 8 , wherein the heat treatment step includes suctioning the exhaust gas into a suction port of the exhaust unit that is provided to face the feeding unit side and provided on a side where the carbonaceous material is discharged, the discharge side of the carbonaceous material to suction the exhaust gas.

10. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery according to claim 9 , wherein in the heating step, a suction port of the furnace reactor tube has a temperature of 600 C or more.

11. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery according to claim 9 , wherein the exhaust gas treatment step further includes a recovery step of filtering the water or aqueous solution in which the exhaust gas has been absorbed and recovering the flying carbonaceous matter in the aqueous solution.

12. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery according to claim 9 , wherein in the heat treatment step, the carbon precursor is fed so that an areal weight is 15 kg/m2 or less.

13. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery according to claim 8 , wherein the exhaust gas treatment step further includes a recovery step of filtering the water or aqueous solution in which the exhaust gas has been absorbed and recovering the flying carbonaceous matter in the aqueous solution.

14. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery according to claim 8 , wherein in the heat treatment step, the carbon precursor is fed so that an areal weight is 15 kg/m2 or less.