Method and device for carrying out a water-gas shift reactor
View Patent ↗A process for performing the water gas shift reaction wherein raw synthesis gas is reacted in the presence of steam and at least one water gas shift catalyst to convert carbon monoxide into carbon dioxide and to form hydrogen. The raw synthesis gas is initially passed through at least one unit for high-temperature CO conversion and subsequently, downstream thereof, passed through at least one unit for low-temperature CO conversion. After passing through the at least one unit for high-temperature CO conversion the synthesis gas stream is divided into at least two substreams. The first substream is passed through a first unit for low-temperature CO conversion and the second substream is passed through a second unit for low-temperature CO conversion, wherein both units for low-temperature CO conversion are arranged in parallel relative to one another.
1. A process for performing a water gas shift reaction, comprising:
reacting raw synthesis gas in the presence of steam and at least one water gas shift catalyst to convert carbon monoxide into carbon dioxide and to form hydrogen,
wherein the raw synthesis gas is initially passed through at least one unit for high-temperature CO conversion and subsequently, downstream thereof, passed through at least two units for low-temperature CO conversion,
wherein after passing through the at least one unit for high-temperature CO conversion the synthesis gas stream is divided into at least two substreams,
wherein the first substream is passed through a first unit for low-temperature CO conversion wherein the first substream comprises a proportion of 95% by volume to 65% by volume of the total synthesis gas stream after the high-temperature CO conversion and the second substream is passed through a second unit for low-temperature CO conversion wherein the second substream comprises a proportion of 5% by volume to 35% by volume of the total synthesis gas stream after the high-temperature CO conversion, wherein both units for low-temperature CO conversion are arranged in parallel relative to one another.
2. The process of claim 1 wherein the entry temperature of the raw synthesis gas into the high-temperature CO conversion is in the range of 350-400° C.
3. The process of claim 1 wherein the maximum exit temperature of the synthesis gas stream from the high-temperature CO conversion is in the range of 430-450° C.
4. The process of claim 1 wherein after exiting the high-temperature CO conversion and before entering the at least two units for low-temperature CO conversion the synthesis gas stream is cooled by means of a cooling unit so that the entry temperature upon entry into the at least two units for low-temperature CO conversion is in the range from 180° C. to 220° C.
5. The process of claim 1 wherein the maximum exit temperature of the synthesis gas stream from the at least two units for low-temperature CO conversion is in the range from 220 to 240° C.
6. The process of claim 1 wherein the entry concentration of carbon monoxide in the raw synthesis gas upon entry into the high-temperature CO conversion is in the range from 10 mol % to 16 mol % and the exit concentration of carbon monoxide in the synthesis gas stream upon exiting the high-temperature CO conversion (2) and upon entering the low-temperature CO conversion is in each case in the range from 3 mol % to 5 mol %.
7. The process of claim 1 wherein the exit concentration of carbon monoxide in the synthesis gas stream upon exiting the low-temperature CO conversion is less than 0.8 mol %.
8. The process of claim 1 wherein the water gas shift reaction in the high-temperature CO conversion is carried out in the presence of an iron-containing catalyst which contains not only iron but also chromium and copper, where the latter are present in the catalyst in smaller amounts than iron.
9. The process of claim 1 wherein the water gas shift reaction in the low-temperature CO conversion is carried out in the presence of a copper-containing catalyst which contains not only copper but also zinc and aluminum, where the latter are present in the catalyst in smaller amounts than copper.