Complex fibers of cellulose fibers with inorganic particles and processes for preparing them
The present invention aims to provide complex fibers of a cellulose fiber with inorganic particles exhibiting better drainage and retention when they are used as materials for forming sheets. In the complexes of the present invention, (1) the weight ratio B/A between the inorganic content (B) in the residue remaining on a 60-mesh sieve (having an opening of 250 μm) after an aqueous suspension of a complex fiber having a solids content of 0.1% is filtered through the sieve and the inorganic content (A) in the complex fiber before treatment is 0.3 or more; or (2) the weight ratio C/A between the inorganic content (C) in fractions corresponding to an effluent volume (L) of 16.00 to 18.50 and an elution time (sec) of 10.6 to 37.3 and the inorganic content (A) in the complex fiber before treatment is 0.3 or more when an aqueous suspension of the complex fiber having a solids content of 0.3% is classified using a fiber classification analyzer under the conditions of a flow rate of 5.7 L/min, a water temperature of 25±1° C., and a total effluent volume of 22 L.
1. A process for preparing a complex fiber of a cellulose fiber with inorganic particles, wherein the inorganic particles comprise BaSO 4 , CaCO 3 or hydrotalcite and the complex fiber has a ratio (B/A or C/A) of 0.3 or more;
wherein said process comprises: synthesizing the inorganic particles in a suspension containing 0.5% to 4.0% of a cellulose fiber to obtain the complex fiber, and analyzing the complex fiber to determine the B/A or the C/A of the complex fiber, wherein:
(1) B/A is determined by: filtering an aqueous suspension of the complex fiber having a solids content of 0.1% through a 60-mesh sieve (having an opening of 250 μm); and calculating B/A in which A is an inorganic content of the complex fiber before the filtration, and B is an inorganic content of the complex fiber obtained after the filtration as the residue remaining on the sieve; and
(2) C/A is determined by: treating an aqueous suspension of the complex fiber having a solids content of 0.3% using a fiber classification analyzer under the conditions of a flow rate of 5.7 L/min, a water temperature of 25±1° C., and a total elution volume of 22 L; and calculating C/A in which A is an inorganic content of the complex fiber before the classification, and C is an the weight ratio C/A between the inorganic content of the complex fiber in fractions corresponding to an elution volume (L) of 16.00 to 18.50 and an elution time (sec) of 10.6 to 37.3.
2. The process of claim 1 , wherein the inorganic particles comprise CaCO 3 , and the inorganic particles are synthesized under the conditions of: Ca ions being 0.01 mol/L to 0.20 mol/L.
3. The process of claim 1 , wherein the inorganic particles comprise BaSO 4 , and the inorganic particles are synthesized under the conditions of: Ba ions being 0.01 mol/L to 0.20 mol/L.
4. The process of claim 1 , wherein the inorganic particles comprise hydrotalcite, and the inorganic particles are synthesized under the conditions of: CO 3 ions being 0.01 mol/L to 0.80 mol/L.
5. The process of claim 1 , wherein the complex fiber has an average fiber length of 0.4 mm or more.
6. The process of claim 1 , wherein the complex fiber has B/A or C/A of 0.5 or more.
7. A process for preparing a complex fiber sheet, comprising forming a sheet from a complex fiber obtained by the process of claim 1 .