IP Library Granted Patent US 11,117,849
Granted Patent B2
US 11,117,849 · App. 16/978,913 · Granted Sep 14, 2021

Method for producing indene

Inventors: Nobuhiro Kimura (Tokyo, JP); Atsushi Segawa (Tokyo, JP)
Assignee: ENEOS CORPORATION
C07C5/3337B01J21/005B01J21/10B01J23/14B01J23/626C07C5/367C07C2521/04C07C2521/10C07C2523/14C07C2523/62
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Quick Facts
Patent No.
US 11,117,849
App. No.
16/978,913
Granted
Sep 14, 2021
Kind
B2
Abstract

The present invention provides a production method for indene, comprising a dehydrogenation step of obtaining a reaction product containing indene by contacting a raw material composition containing indene with a dehydrogenation catalyst, wherein the dehydrogenation catalyst comprises a support containing aluminum, and a group 14 metal element and platinum supported on the support, a content of the platinum in the dehydrogenation catalyst is 0.6 to 2.5% by mass based on a whole amount of the dehydrogenation catalyst, and an atomic ratio of the group 14 metal element to the platinum in the dehydrogenation catalyst is 4.0 to 20.0.

Claims (9)

1. A production method for indene, comprising a dehydrogenation step of obtaining a reaction product containing indene by contacting a raw material composition containing indane with a dehydrogenation catalyst,

wherein the dehydrogenation catalyst comprises a support containing aluminum, and a group 14 metal element and platinum supported on the support,

a content of the platinum in the dehydrogenation catalyst is 0.6 to 2.5% by mass based on a whole amount of the dehydrogenation catalyst, and

an atomic ratio of the group 14 metal element to the platinum in the dehydrogenation catalyst is 4.0 to 20.0.

2. The production method according to claim 1 , wherein the atomic ratio of the group 14 metal element to the platinum in the dehydrogenation catalyst is 7.0 to 20.0.

3. The production method according to claim 1 , wherein the group 14 metal element is tin.

4. The production method according to claim 1 , wherein the group 14 metal element and the platinum are supported on the support by using a metal source not containing a chlorine atom.

5. The production method according to claim 1 , wherein a mole fraction of the indane in the raw material composition is 0.2 or more.

6. The production method according to claim 1 , further comprising a raw material synthesis step of obtaining indane by dehydrogenation reaction of tetrahydroindene.

Assignments (2)
CHANGE OF NAME Recorded Jun 4, 2021
From: JXTG NIPPON OIL & ENERGY CORPORATION
To: ENEOS CORPORATION
Reel/Frame 056476/0748 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 8, 2020
From: KIMURA, NOBUHIRO; SEGAWA, ATSUSHI
To: ENEOS CORPORATION
Reel/Frame 053712/0868 →
Priority Claims (1)
JP JP2018-045606 · Mar 13, 2018 · national
Continuity (1)
Related Publication 20210047248A1 · Feb 18, 2021