Carbon nanotube dispersion liquid, slurry for secondary battery electrode, method of producing slurry for secondary battery electrode, electrode for secondary battery, and secondary battery
Disclosed is a carbon nanotube dispersion liquid containing carbon nanotubes, a binder, and a dispersion medium. The binder includes a polymer (A) containing an aromatic vinyl monomer unit and a linear alkylene structural unit having a carbon number of at least 4. The proportion of the binder in the carbon nanotube dispersion liquid is 30 mass % or less, and the viscosity change rate of the carbon nanotube dispersion liquid as measured under predetermined conditions before and after leaving the carbon nanotube dispersion liquid for 1 week is 50% or more and 300% or less.
1. A carbon nanotube dispersion liquid containing carbon nanotubes, a binder, and a dispersion medium, wherein
the binder is free of a water-soluble polymer and includes a polymer (A) containing an aromatic vinyl monomer unit and a linear alkylene structural unit having a carbon number of at least 4,
a proportion of the binder relative to a total solid content of the carbon nanotube dispersion liquid is 30 mass % or less,
a viscosity change rate of the carbon nanotube dispersion liquid as measured under conditions of a temperature of 25° C. and a shear rate of 0.1 s −1 before and after leaving the carbon nanotube dispersion liquid for 1 week is 50% or more and 240% or less,
the polymer (A) contains the aromatic vinyl monomer unit in an amount of 35 mass % or more and 60 mass % or less and the linear alkylene structural unit having a carbon number of at least 4 in an amount of 25 mass % or more and 35 mass % or less,
the polymer (A) has an iodine value of 50 mg/100 mg or less,
the polymer (A) has a weight-average molecular weight of 5,000 or more and 300,000 or less,
a specific surface area of the carbon nanotubes is 50 m 2 /g or more and 400 m 2 /g or less, and
the dispersion medium includes at least N-methyl-2-methylpyrrolidone.
2. A slurry for a secondary battery electrode comprising an electrode active material and the carbon nanotube dispersion liquid as recited in claim 1 .
3. A method of producing the slurry for a secondary battery electrode as recited in claim 2 , comprising:
a first step of mixing the carbon nanotubes, the binder, and the dispersion medium to obtain a carbon nanotube dispersion liquid; and
a second step of mixing the carbon nanotube dispersion liquid and the electrode active material.
4. An electrode for a secondary battery comprising an electrode mixed material layer formed using the slurry for a secondary battery electrode as recited in claim 2 .
5. A secondary battery comprising the electrode for a secondary battery as recited in claim 4 .
6. The carbon nanotube dispersion liquid according to claim 1 , wherein the binder consists of the polymer (A) and optionally a polymer (B) selected from a group consisting of a fluorine-containing polymer, polyacrylonitrile, and a combination thereof.