High performance single-component hot melt sealant composition
The subject of the present invention relates to an improved high performance, hot melt, single-component sealant composition comprising: (a) an elastomer selected from butyl rubber, polyisobutylene rubber, ethylene-propylene rubber, and mixtures thereof, (b) an inorganic filler, and (c) an adhesion promoter comprising an epoxy-based silane and an amino-based silane, wherein the weight ratio between the epoxy-based silane and the amino-based silane ranges from 60/40 to 90/10. The present invention also relates to the use of said sealant composition as an edge sealant in insulating glass structures, such as windows or doors. Finally, the invention relates to an insulated glass structure comprising a sealant composition according to the invention.
1. A sealant composition comprising:
(a) an elastomer selected from butyl rubber, polyisobutylene rubber, ethylene-propylene rubber, and mixtures thereof,
(b) an inorganic filler, and
(c) an adhesion promoter comprising an epoxy-based silane and an amino-based silane, wherein the weight ratio between the epoxy-based silane and the amino-based silane ranges from 60/40 to 90/10.
2. The composition according to claim 1 , wherein the inorganic filler comprises calcium carbonate.
3. The composition according to claim 2 , wherein the inorganic filler is a mixture of precipitated calcium carbonate and ground calcium carbonate, and wherein the weight ratio between the precipitated calcium carbonate and the ground calcium carbonate ranges from 50/50 to 30/70.
4. The composition according to claim 2 , wherein the inorganic filler is a mixture of precipitated calcium carbonate and ground calcium carbonate.
5. The composition according to claim 1 , wherein the epoxy-based silane is of formula (I) or (II):
wherein:
R and R′, the same or different, represent a linear or branched C 1 to C 4 alkyl group,
n is an integer equal to 1, 2, 3 or 4, and
x is an integer equal to 0, 1 or 2.
6. The composition according to claim 5 , wherein the epoxy-based silane is selected from 3-glycidoxyethyltrimethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3-glycidoxypropyltriethoxysilane, 2-(3,4-epoxycyclohexyl)propyltrimethoxysilane, 2-(3,4-epoxycyclohexyl)ethylmethyldimethoxysilane, and mixtures thereof.
7. The composition according to claim 1 , wherein the amino-based silane is of formula (III):
wherein:
R and R′, the same or different, represent a linear or branched C 1 to C 4 alkyl group,
R″ represents a hydrogen atom, a linear, branched or cyclic C 1 to C 8 alkyl group, or C 4 to C 8 alkylaryl or aromatic group, or a —([CH 2 ] q —NH) n′ —H group,
n is an integer equal to 1, 2, 3 or 4,
n′ is an integer equal to 0, 1, 2, 3 or 4,
p is an integer equal to 2, 3 or 4,
q is an integer equal to 2, 3 or 4, and
x is an integer equal to 0, 1 or 2.
8. The composition according to claim 7 , wherein the amino-based silane is selected from N-(2-aminoethyl)-3-aminopropyltriethoxysilane, N-(2-aminoethyl)-3-aminopropyltrimethoxysilane, N-[3-(trimethoxysilyl)propyl]ethylenediamine, 3-aminopropyltriethoxysilane, 3-aminopropyltrimethoxysilane, 3-aminopropylmethyldiethoxysilane, N-methylaminopropyltrimethoxysilane, and mixtures thereof.
9. The composition according to claim 1 , wherein the weight ratio between the epoxy-based silane and the amino-based silane ranges from 70/30 to 80/20.
10. The composition according to claim 1 , wherein the adhesion promoter (c) is a mixture of 3-glycidoxypropyltrimethoxysilane and N-[3-(trimethoxysilyl)propyl]ethylenediamine.
11. The composition according to claim 1 , further comprising:
(d) a thermoplastic polymer selected from amorphous poly-alpha-olefin polymer, copolymer of ethylene and vinyl acetate, copolymer of ethylene and ethyl acrylate, copolymer of ethylene and acrylic acid, polyethylene, polypropylene, polyamide styrene-butadiene-styrene and styrene-isoprene-styrene block copolymers, and mixtures thereof.
12. The composition according to claim 1 , further comprising:
(e) a pigment.
13. The composition according to claim 1 , further comprising:
(f) tackifier resin.
14. The composition according to claim 1 , further comprising:
(g) an antioxidant stabilizer.
15. The composition according to claim 1 , comprising:
(a) 5 to 65 wt % of at least one elastomer selected from butyl rubber, polyisobutylene rubber, ethylene-propylene rubber, and mixture thereof,
(b) 10 to 60 wt % of at least one inorganic filler,
(c) 0.1 to 5 wt % of an adhesion promoter comprising an epoxy-based silane and an amino-based silane, wherein the weight ratio between the epoxy-based silane and the amino-based silane ranges from 60/40 to 90/10,
(d) 2 to 30 wt % of at least one thermoplastic polymer,
(e) 0 to 5 wt % of at least one pigment,
(f) 5 to 50 wt % of at least one tackifier resin,
(g) 0.1 to 3 wt % of at least one antioxidant stabilizer, in which the sum of components (a), (b), (c), (d), (e), (f) and (g) is 100 wt %.
16. The composition according to claim 1 , wherein the weight ratio between the epoxy-based silane and the amino-based silane ranges from 65/35 to 85/15.
17. A method for insulating a glass structure, comprising sealing an edge of said glass structure with the sealant composition according to claim 1 .
18. An insulated glass structure comprising two parallel panes of glass separated by a spacer bar, wherein the two panes of glass are bonded to the spacer bar through the sealant composition according to claim 1 .
19. An insulated glass structure comprising three parallel panes of glass separated by one or two spacer bars, wherein the three panes of glass are bonded to the spacer bar(s) through the sealant composition according to claim 1 .