Graphene reinforced polyethylene terephthalate
A composition and a method are provided for graphene reinforced polyethylene terephthalate (PET). Graphene nanoplatelets (GNPs) comprising multi-layer graphene are used to reinforce PET, thereby improving the properties of PET for various new applications. Master-batches comprising polyethylene terephthalate with dispersed graphene nanoplatelets are obtained by way of compounding. The master-batches are used to form PET-GNP nanocomposites at weight fractions ranging between 0.5% and 15%. In some embodiments, PET and GNPs are melt compounded by way of twin-screw extrusion. In some embodiments, ultrasound is coupled with a twin-screw extruder so as to assist with melt compounding. In some embodiments, the PET-GNP nanocomposites are prepared by way of high-speed injection molding. The PET-GNP nanocomposites are compared by way of their mechanical, thermal, and rheological properties so as to contrast different compounding processes.
1. A graphene reinforced polyethylene terephthalate nanocomposite, comprising:
a polymer matrix comprising polyethylene terephthalate; and
graphene nanoplatelets compounded into the polyethylene terephthalate, wherein the graphene nanoplatelets are exfoliated, and the graphene reinforced polyethylene terephthalate nanocomposite comprises the graphene nanoplatelets in weight fractions ranging from 5% to 15%, and
an average interparticle distance for graphene nanoplatelets inside the polyethylene terephthalate matrix ranges from 520 to 2800 nm.
2. The nanocomposite according to claim 1 , wherein the graphene reinforced polyethylene terephthalate nanocomposite comprises the graphene nanoplatelets at a 5% weight fraction and having an average interparticle distance of 2800 nm.
3. The nanocomposite according to claim 1 , wherein the graphene reinforced polyethylene terephthalate nanocomposite comprises the graphene nanoplatelets at a 15% weight fraction and having an average interparticle distance of 520 nm.
4. The nanocomposite according to claim 1 , wherein the graphene nanoplatelets have a thickness of about 6 nm to about 8 nm.
5. The nanocomposite according to claim 1 , wherein the graphene nanoplatelets have a diameter of 5 μm and an average surface area of 120 m 2 /g to 150 m 2 /g.
6. The nanocomposite according to claim 1 , wherein the graphene nanoplatelets have an aspect ratio of 40.