Methods, materials systems, and devices for inhibiting infiltration and penetration of molten salts into solid materials
Methods, materials systems, and devices for inhibiting the infiltration and penetration of molten salts into solid materials, including porous materials at temperatures above the solidus temperature of the molten salt. The methods, materials systems, and devices utilize a non-wetted solid that is introduced into pores having entrances at an exterior surface of a porous solid material adapted to contact the molten salt.
1. A method for enhancing the resistance of a porous solid material to the infiltration and penetration of a molten salt, the method comprising:
providing a porous solid material having an exterior surface adapted to contact the molten salt and pores having entrances at the exterior surface; and
introducing into the pores of the porous solid material a non-wetted solid that is not infiltrated or penetrated by the molten salt;
wherein the non-wetted solid is introduced into the pores of the porous solid material by the infiltration of a fluid precursor material to the non-wetted solid into the pores of the porous solid material, followed by conversion of the fluid precursor material into the non-wetted solid within the pores of the porous solid material; and
wherein the fluid precursor material to the non-wetted solid comprises a vapor precursor material and the conversion of the vapor precursor material to the non-wetted solid is conducted by one or more of condensation of the vapor precursor material onto the internal surfaces of the porous solid material and a thermal treatment to allow the vapor precursor material to undergo a chemical reaction.
2. The method of claim 1 , wherein the non-wetted solid is a hydrophobic solid.
3. The method of claim 1 , wherein the non-wetted solid is a carbon-bearing solid, or a hydrocarbon-bearing solid, or a mixture thereof.
4. The method of claim 1 , wherein the fluid precursor material to the non-wetted solid further comprises a liquid precursor material to the non-wetted solid, or a mixture of liquid and solid precursor materials to the non-wetted solid.
5. The method of claim 1 , wherein the fluid precursor material comprises pitch, tar, or a mixture thereof.
6. The method of claim 1 , wherein the fluid precursor material is produced from a natural source or from a manufactured source, wherein the natural source or manufactured source is one of a plant, peat, coal, coal tar, pitch, charcoal, petroleum, or any combination of two or more thereof.
7. The method of claim 4 , wherein the conversion of the liquid precursor material to the non-wetted solid, or the conversion of the mixture of liquid and solid precursor materials to the non-wetted solid, is conducted by a thermal treatment.
8. The method of claim 1 , wherein the non-wetted solid is present within the pores of the porous solid material and is not present solely as a continuous uninterrupted external layer on the exterior surface of the porous solid material.
9. The method of claim 8 , wherein the non-wetted solid only penetrates a portion of a thickness of the porous solid material to completely close, or to partially close, the entrances of the pores at the exterior surface of the porous solid material, and a bulk of the porous solid material remains porous.
10. The method of claim 1 , wherein the porous solid material comprises a porous metal, a porous metal alloy, a porous ceramic, a porous ceramic alloy, or a porous mixture of two or more of a porous metal alloy, a porous ceramic, or a porous ceramic alloy.