IP Library Granted Patent US 11,545,620
Granted Patent B2
US 11,545,620 · App. 16/996,573 · Granted Jan 3, 2023

Methods of manufacture precessional spin current magnetic tunnel junction devices

Inventors: Bartlomiej Kardasz (Fremont, CA); Jorge Vasquez (Fremont, CA); Mustafa Pinarbasi (Fremont, CA)
Assignee: Integrated Silicon Solution, (Cayman) Inc.
H01L43/08H01L43/02H01L43/12H01L27/222H01L43/10
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Quick Facts
Patent No.
US 11,545,620
App. No.
16/996,573
Granted
Jan 3, 2023
Kind
B2
Abstract

A Magnetic Tunnel Junction (MTJ) device can include a second Precessional Spin Current (PSC) magnetic layer of Ruthenium (Ru) having a predetermined thickness and a predetermined smoothness. An etching process for smoothing the PSC magnetic layer can be performed in-situ with various deposition processes after a high temperature annealing of the MTJ formation.

Claims (45)

1. A Magnetic Tunnel Junction (MTJ) device comprising:

a Synthetic Antiferromagnetic (SAF) formation disposed on a substrate;

a MTJ formation disposed on the SAF formation;

a first Precessional Spin Current (PSC) magnetic layer disposed on the MTJ formation, wherein the first PSC magnetic layer includes Iron (Fe) and has a thickness of approximately 0.4-1 nanometers (nm);

a second PSC magnetic layer disposed on the first PSC magnetic layer, wherein the second PSC magnetic layer includes Ruthenium (Ru) and has a thickness of approximately 0.5-3 nm and a smoothness of approximately 0.2 nm; and

a third PSC magnetic layer disposed on the second PSC magnetic layer, wherein the third PSC magnetic layer includes one or more of Cobalt (Co), Iron (Fe) and Boron (B) and has a thickness of approximately 1-5 nm.

2. The MTJ device of claim 1 , wherein the MTJ formation comprises:

a reference magnetic layer disposed on the SAF formation, wherein the reference magnetic layer includes one or more of Cobalt (Co), Iron (Fe) and Boron (B), Cobalt Nickel (CoNi), Cobalt Platinum (CoPt) and has a thickness of approximately 1-5 nm;

a non-magnetic tunneling barrier layer disposed on the reference magnetic layer, wherein the non-magnetic tunneling barrier layer includes Magnesium (Mg) oxide and has a thickness of approximately 1-10 nm; and

a free magnetic layer disposed on the non-magnetic tunneling barrier layer, wherein the free magnetic layer includes one or more of Cobalt (Co), Iron (Fe) and Boron (B) and has a thickness of approximately 1-3 nm.

3. The MTJ device of claim 1 , wherein the SAF formation comprises:

a first ferromagnetic layer disposed on the substrate, wherein the first ferromagnetic layer includes one or more of Cobalt (Co), Cobalt Nickel (CoNi) and Cobalt Platinum (CoPt)) and has a thickness of approximately 1-5 nm; and

a first non-magnetic layer disposed on the first ferromagnetic layer, wherein the first non-magnetic layer includes Ruthenium (Ru) and has a thickness of approximately 0.9 nm.

4. The MTJ device of claim 1 , further comprising:

a PSC coupling layer disposed between the MTJ formation and the first PSC magnetic layer, wherein the PSC coupling layer includes one or more of Ruthenium (Ru), Tantalum (Ta), Copper (Cu), Copper Nitride (CuN), and Magnesium oxide (MgO) and has a thickness of approximately 1-20 nm.

5. The MTJ device of claim 1 , further comprising:

a Perpendicular Magnetic Anisotropy (PMA) enhancement layer disposed between the MTJ formation and the first PSC magnetic layer, wherein the PMA enhancement layer includes one or more of Cobalt (Co), Iron (Fe), Boron (B) and Tantalum Nitride (TaN) and has a thickness of approximately 0.5-2 nm.

6. The MTJ device of claim 1 , further comprising:

one or more capping layers disposed on the third PSC magnetic layer.

7. The MTJ device of claim 1 , further comprising:

one or more seed layers disposed between the substrate and the SAF formation.

8. The MTJ device of claim 1 , wherein the MTJ device comprises a Magnetoresistive Random Access Memory (MRAM).

9. A Magnetic Tunnel Junction (MTJ) device comprising:

a reference magnetic layer;

a non-magnetic tunneling barrier layer disposed on the reference magnetic layer;

a free magnetic layer disposed on the non-magnetic tunneling barrier layer;

a first Precessional Spin Current (PSC) magnetic layer disposed on the free magnetic layer;

a second PSC magnetic layer disposed on the first PSC magnetic layer, wherein the second PSC magnetic layer includes Ruthenium (Ru) and has a thickness of approximately 0.5-3 nm and a smoothness of approximately 0.2 nm; and

a third PSC magnetic layer disposed on the second PSC magnetic layer, wherein the third PSC magnetic layer includes one or more of Cobalt (Co), Iron (Fe) and Boron (B) and has a thickness of approximately 1-5 nm.

10. The MTJ device of claim 9 , further comprising:

a PSC coupling layer disposed between the free magnetic layer and the first PSC magnetic layer, wherein the PSC coupling layer includes one or more of Ruthenium (Ru), Tantalum (Ta), Copper (Cu), Copper Nitride (CuN), and Magnesium oxide (MgO) and has a thickness of approximately 1-20 nm.

11. The MTJ device of claim 10 , further comprising:

one or more capping layers disposed on the third PSC magnetic layer.

12. The MTJ device of claim 11 , wherein:

the reference magnetic layer includes one or more of Cobalt (Co), Iron (Fe) and Boron (B), Cobalt Nickel (CoNi), Cobalt Platinum (CoPt) and has a thickness of approximately 1-5 nm;

the non-magnetic tunneling barrier layer includes Magnesium (Mg) oxide and has a thickness of approximately 1-10 nm; and

the free magnetic layer includes one or more of Cobalt (Co), Iron (Fe) and Boron (B) and has a thickness of approximately 1-3 nm.

13. The MTJ device of claim 9 , further comprising:

a Perpendicular Magnetic Anisotropy (PMA) enhancement layer disposed between the free magnetic layer and the first PSC magnetic layer, wherein the PMA enhancement layer includes one or more of Cobalt (Co), Iron (Fe), Boron (B) and Tantalum Nitride (TaN) and has a thickness of approximately 0.5-2 nm.

14. The MTJ device of claim 13 , further comprising:

one or more capping layers disposed on the third PSC magnetic layer.

15. The MTJ device of claim 14 , wherein:

the reference magnetic layer includes one or more of Cobalt (Co), Iron (Fe) and Boron (B), Cobalt Nickel (CoNi), Cobalt Platinum (CoPt) and has a thickness of approximately 1-5 nm;

the non-magnetic tunneling barrier layer includes Magnesium (Mg) oxide and has a thickness of approximately 1-10 nm; and

the free magnetic layer includes one or more of Cobalt (Co), Iron (Fe) and Boron (B) and has a thickness of approximately 1-3 nm.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 3, 2021
From: SPIN (ASSIGNMENT FOR BENEFIT OF CREDITORS), LLC
To: INTEGRATED SILICON SOLUTION, (CAYMAN) INC.
Reel/Frame 057407/0829 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 20, 2021
From: SPIN MEMORY, INC.
To: SPIN (ASSIGNMENT FOR THE BENEFIT OF CREDITORS), LLC
Reel/Frame 056927/0038 →
Continuity (2)
Division 15859243 · Dec 29, 2017
Related Publication 20200411752A1 · Dec 31, 2020