Porous devices and processes for producing same
A method for making a polymer with a porous layer from a solid piece of polymer is disclosed. In various embodiments, the method includes heating a surface of a solid piece of polymer to a processing temperature and holding the processing temperature while displacing a porogen layer through the surface of the polymer to create a matrix layer of the solid polymer body comprising the polymer and the porogen layer. In at least one embodiment, the method also includes removing at least a portion of the layer of porogen from the matrix layer to create a porous layer of the solid piece of polymer.
1. A medical device, comprising:
a solid thermoplastic body having at least two porous surface layers that are on opposite faces of the solid thermoplastic body, the at least two porous surface layers comprising pores extending into the solid thermoplastic body for a defined distance; and
a body layer that is between the at least two porous surface layers;
wherein the at least two porous surface layers have increased wettability in comparison to the body layer and the interconnectivity of the pores is about 99%.
2. The medical device of claim 1 , wherein the solid thermoplastic body comprises polyetheretherketone (PEEK).
3. The medical device of claim 1 , wherein the expulsion resistance of the medical device is at least about 1.5 times greater than the expulsion resistance of a medical device of a similar material with no porous surface layers.
4. The medical device of claim 1 , wherein the defined distance is approximately 0.7 mm.
5. The medical device of claim 1 , further comprising at least one marker for detecting tissue ingrowth into the medical device.
6. The medical device of claim 1 , wherein an interfacial shear strength between the body layer and each of the at least two porous surface layers is at least about 17 MPa.
7. A medical device, comprising:
a thermoplastic body having a porous layer formed from a plurality of pores on a surface of the thermoplastic body, the porous layer being adjacent a solid body layer, the porous layer extending a defined distance from the surface of the thermoplastic body, wherein the porous layer has a particular wettability, wherein the particular wettability is greater than a wettability of the solid body layer;
an interconnectivity between the plurality of pores is at least 99%; and
an interfacial shear strength between the porous layer and the body is at least about 17 MPa.
8. The medical device of claim 7 , wherein the thermoplastic body comprises polyetheretherketone (PEEK).
9. The medical device of claim 8 , wherein: the body layer comprises a first particular percentage of hydroxyl groups; and the porous layer comprises a second particular percentage of hydroxyl groups, wherein the second particular percentage of hydroxyl groups is greater than the first particular percentage of hydroxyl groups.
10. The medical device of claim 9 , wherein: the body layer comprises a first particular carbon to oxygen atomic ratio; and the porous layer comprises a second particular carbon to oxygen atomic ratio, wherein the second particular carbon to oxygen atomic ratio is substantially the same as the first particular carbon to oxygen atomic ratio.
11. The medical device of claim 10 , further comprising at least one marker for detecting the medical device on an x-ray.
12. The medical device of claim 11 , wherein the at least one marker is a tantalum marker inserted into a portion of the thermoplastic body.
13. The medical device of claim 12 , wherein: the thermoplastic body further includes a second porous layer formed from a plurality of pores on a second surface of the thermoplastic body, the second porous layer extending a second defined distance from the second surface into the thermoplastic body.
14. The medical device of claim 13 , wherein the second defined distance is approximately 0.5 mm to 1.0 mm.
15. The medical device of claim 14 , wherein the second defined distance is approximately 0.7 mm.