Lubricant compositions for direct injection engine
The invention is directed to a method for reducing low speed pre-ignition events in a spark-ignited direct injection internal combustion engine by supplying to the sump a lubricant composition which contains an oil of lubricating viscosity and an ashless dispersant. The ashless dispersant may be selected from succinimide compounds prepared from aliphatic or aromatic amines.
1. A lubricant composition comprising:
a base oil of lubricating viscosity;
0.5 to 2.2 wt % of a boron-containing polyisobutenyl succinimide ashless dispersant having a TBN of 30 to 70 and delivering 80 to 350 ppm of boron to the lubricating composition;
1.0 to 3.0 wt % of a boron-free polyisobutenyl succinimide dispersant having a TBN of 30 to 70;
0.2 to 0.5 wt % of a sulfurized olefin antioxidant;
0.2 to 1 wt % of a magnesium sulfonate detergent having a TBN of 300 to 500;
0.4 to 1.1 wt % of a zinc dialkyldithiophosphate antiwear agent; and
0.2 to 3 wt % of a calcium alkylbenzene sulfonate detergent.
2. The composition of claim 1 , wherein the engine is operated under a load with a brake mean effective pressure (BMEP) of greater than or equal to 10 bars.
3. The composition of claim 1 , wherein the engine is operated at speeds less than or equal to 3,000 rpm.
4. The composition of claim 1 , wherein the engine is fueled with a liquid hydrocarbon fuel, a liquid non-hydrocarbon fuel, or mixtures thereof.
5. The composition of claim 4 , wherein the engine is fueled by natural gas, liquefied petroleum gas (LPG), compressed natural gas (CNG), or mixtures thereof.
6. The composition of claim 1 , wherein the lubricant composition further comprises at least one other additional additive selected from a metal containing overbased detergent, a phosphorus-containing anti-wear additive, a friction modifier, and a polymeric viscosity modifier.
7. The method of claim 1 , wherein the lubricating composition comprises at least 50 weight % of Group II base oil, Group III base oil, or mixtures thereof.
8. A lubricant composition comprising:
a base oil of lubricating viscosity;
0.5 to 2.2 wt % of a boron-containing polyisobutenyl succinimide ashless dispersant having a TBN of 30 to 70 and delivering 80 to 350 ppm of boron to the lubricating composition;
1.0 to 3.0 wt % of a boron-free polyisobutenyl succinimide dispersant having a TBN of 30 to 70;
0.2 to 0.5 wt % of a sulfurized olefin antioxidant;
0.2 to 1 wt % of a magnesium sulfonate detergent having a TBN of 300 to 500;
0.4 to 1.1 wt % of a zinc dialkyldithiophosphate antiwear agent; and
0.2 to 3 wt % of a calcium alkylbenzene sulfonate detergent, wherein the lubricating composition is capable of reducing low speed pre-ignition events in a spark-ignited direct injection internal combustion engine operated under a load with a brake mean effective pressure (BMEP) of greater than or equal to 10 bars.