Separator including porous substrate layer, metal oxide intermediate layer, and ceramic coating layer, method of preparing the same and lithium-ion battery including the same
A separator including a porous substrate layer, an intermediate layer, and a ceramic coating layer is provided. The ceramic coating layer is disposed on a side of the intermediate layer away from the porous substrate layer. The intermediate layer includes a metal oxide powder. The particle diameter of the metal oxide powder is less than the pore diameter of the porous substrate layer, and at least a portion of the metal oxide powder is embedded in the porous substrate layer. A method of preparing the separator and a lithium-ion battery including the separator are also provided.
1. A separator, comprising:
a porous substrate layer;
an intermediate layer, wherein the intermediate layer comprises a metal oxide powder, a particle diameter of the metal oxide powder is less than a pore diameter of the porous substrate layer, and at least a portion of the metal oxide powder is embedded in the porous substrate layer; and
a ceramic coating layer, wherein the ceramic coating layer is disposed on a side of the intermediate layer away from the porous substrate layer, wherein the ceramic coating layer comprises ceramic material particles, the ceramic material particles comprise 5 to 10 parts by weight of small particles, 30 to 70 parts by weight of medium particles, and 5 to 10 parts by weight of large particles,
the small particles are ceramic material particles with D50=0.8 μm, the medium particles are ceramic material particles with D50=3.6 μm, and the large particles are ceramic material particles with D50=9.2 μm.
2. The separator according to claim 1 , wherein the porous substrate layer comprises one or plural of polyethylene, polypropylene, and polyamide.
3. The separator according to claim 1 , wherein the intermediate layer has a thickness of less than or equal to 10 nm and a surface density of 0.01 to 0.08 g/m 2 .
4. The separator according to claim 1 , wherein the ceramic coating layer has a thickness of 2 to 5 m and a surface density of 3.5 to 4.5 g/m 2 .
5. The separator according to claim 1 , wherein the ceramic coating layer further comprises an aqueous binder.
6. The separator according to claim 1 , wherein the ceramic coating layer comprises a ceramic material, and wherein a metal oxide of the metal oxide powder is identical to or different from the ceramic material;
the metal oxide is selected from one or plural of Al 2 O 3 , SiO 2 , TiO 2 , and ZrO 2 , and the ceramic material is selected from one or plural of Al 2 O 3 , SiO 2 , TiO 2 , ZrO 2 , and BN.
7. The separator according to claim 6 , wherein the metal oxide is Al 2 O 3 , and the ceramic material is Al 2 O 3 .
8. The separator according to claim 1 , wherein the particle diameter of the metal oxide powder is less than or equal to 10 nm.
9. The separator according to claim 8 , wherein the ceramic coating layer comprises a ceramic material, and wherein a metal oxide of the metal oxide powder is identical to or different from the ceramic material;
the metal oxide is selected from one or plural of Al 2 O 3 , SiO 2 , TiO 2 , and ZrO 2 , and the ceramic material is selected from one or plural of Al 2 O 3 , SiO 2 , TiO 2 , ZrO 2 , and BN.
10. The separator according to claim 9 , wherein the metal oxide is Al 2 O 3 , and the ceramic material is Al 2 O 3 .
11. A lithium-ion battery, comprising the separator according to claim 1 .
12. The lithium-ion battery according to claim 11 , wherein the intermediate layer has a thickness of less than or equal to 10 nm and a surface density of 0.01 to 0.08 g/m 2 .
13. The lithium-ion battery according to claim 11 , wherein the ceramic coating layer has a thickness of 2 to 5 m and a surface density of 3.5 to 4.5 g/m 2 .
14. The lithium-ion battery according to claim 11 , wherein the particle diameter of the metal oxide powder is less than or equal to 10 nm.
15. A method of preparing the separator according to claim 1 , comprising:
depositing the metal oxide powder on a surface of the porous substrate layer through plasma physical vapor deposition to form the intermediate layer,
wherein the particle diameter of the metal oxide powder is less than the pore diameter of the porous substrate layer, and
the portion of the metal oxide powder is embedded in the porous substrate layer; and
forming the ceramic coating layer on a surface of the intermediate layer.
16. The method of preparing the separator according to claim 15 , wherein the intermediate layer has a thickness of less than or equal to 10 nm and a surface density of 0.01 to 0.08 g/m 2 .
17. The method of preparing the separator according to claim 15 , wherein the particle diameter of the metal oxide powder is less than or equal to 10 nm.