Turbine engine shaft coating
A coated steel substrate has a steel substrate having a surface. A coating layer is atop the surface. The coating layer includes: aluminum activated by indium; and a ceramic binder. The coating also may comprise of multiple layers with different properties to facilitate the galvanic protection capability.
1. A coated steel substrate comprising:
a steel substrate having a surface;
a coating layer atop the surface; and
an under-layer between the surface and the coating layer,
wherein:
the coating layer comprises:
aluminum activated by indium; and
a ceramic binder; and
the under-layer comprises:
a ceramic binder and aluminum alloy in a naturally passivated state relative to the aluminum activated by indium of the coating layer.
2. The coated steel substrate of claim 1 wherein the coating layer comprises:
5% to 40% porosity.
3. The coated steel substrate of claim 1 wherein the coating layer comprises, by weight:
0.5% to 40% ceramic binder including up to 2% impurities and additives; and
60% to 97.5% aluminum alloy.
4. The coated steel substrate of claim 3 wherein:
the aluminum alloy is at least 90% aluminum by weight.
5. The coated steel substrate of claim 3 wherein:
the aluminum alloy is 0.01% to 3.0% indium by weight.
6. The coated steel substrate of claim 1 wherein the coating layer comprises:
zinc.
7. The coated steel substrate of claim 1 wherein:
the ceramic binder comprises an alkali metal silicate.
8. The coated steel substrate of claim 1 wherein:
the aluminum activated by indium comprises an Al—In alloy.
9. The coated steel substrate of claim 1 wherein the aluminum activated by indium comprises:
aluminum or an aluminum alloy; and
indium oxide.
10. The coated steel substrate of claim 1 wherein:
the under-layer has a lower indium content than the coating layer; and
the under-layer and the coating layer are each at least 20 micrometers thick.
11. The coated steel substrate of claim 1 wherein:
the under-layer has porosity of 7% to 25%;
the coating layer has porosity of 15% to 38%; and
the coating layer is more porous than the under-layer.
12. A gas turbine engine or other turbomachine including the coated steel substrate of claim 1 as a shaft.
13. A method for manufacturing the coated steel substrate of claim 1 , the method comprising:
depositing the under-layer; and
forming the coating layer by:
applying in one or more slurries:
the aluminum of said aluminum activated by indium; and
one or more precursors of the ceramic binder of the coating layer; and
heating to vaporize a carrier of the one or more slurries.
14. The method of claim 13 wherein:
the aluminum of said aluminum activated by indium is applied as said aluminum activated by indium as at least one of an Al—In or an Al—Zn—In.
15. The method of claim 13 wherein:
the one or more precursors comprise glass formers comprising one or more of Na 2 O, K 2 O, and silica.
16. The method of claim 13 wherein:
the one or more slurries comprise indium oxide and activate the aluminum of the one or more slurries to form the aluminum activated by indium.
17. A coated steel substrate comprising:
a steel substrate having a surface; and
a coating atop the surface,
wherein the coating comprises:
a first layer comprising aluminum and a ceramic binder; and
a second layer comprising a ceramic binder and at least 78% by weight aluminum activated by indium,
wherein:
the aluminum of the first layer is in a naturally passivated state and less active than the aluminum activated by indium of the second layer; and
the first layer between the substrate and the second layer.
18. The coated steel substrate of claim 17 wherein:
the ceramic binder in the first ceramic coating layer and the ceramic binder in the second ceramic coating layer each comprise an alkali metal silicate.
19. The coated steel substrate of claim 17 wherein:
the first layer has a lower indium content than the second layer; and
the first layer and the second layer are each at least 10 micrometers thick.
20. The coated steel substrate of claim 17 being a turbomachine shaft.
21. A coated steel substrate comprising:
a steel substrate having a surface; and
a coating atop the surface,
wherein the coating comprises:
a first layer at least 10 micrometers thick and comprising aluminum and a ceramic binder; and
a second layer at least 10 micrometers thick and comprising a ceramic binder and at least 78% by weight aluminum activated by indium, the first layer between the substrate and the second layer, the first layer having, if any, an indium content at most 50% of an indium content of the second layer.
22. The coated steel substrate of claim 21 being a turbomachine shaft,
the aluminum activated by indium is 0.01% to 3.0% indium by weight.