Integrated catalyst system for stoichiometric-burn natural gas vehicles and preparation method therefor
Disclosed in the present invention is an integrated catalyst system for stoichiometric-burn natural gas vehicles, the catalyst system consisting of a three-way catalyst, a molecular sieve catalyst, and a base body, the three-way catalyst and the molecular sieve catalyst being coated on a surface of the base body. In the integrated three-way catalyst and molecular sieve catalyst system of the present invention, at the same time that pollutants such as CO, HC, and NO x in the exhaust of stoichiometric-burn natural gas vehicles are processed, the produced byproduct NH 3 can also be processed, and the conversion rates of CO, HC, NO x , and NH 3 are high.
1. An integrated catalyst system for a stoichiometric-burn natural gas vehicle, wherein the catalyst system comprises a base body and one or more coatings thereon comprising a three-way catalyst and a molecular sieve catalyst,
the three-way catalyst comprises platinum, palladium, rhodium and a first carrier comprising lanthanum-modified aluminum oxide and a ceria-zirconia solid solution, wherein a weight ratio of the platinum, the palladium and the rhodium in the three-way catalyst is (0.2-0.5):(0.5-0.8):(0.05-0.2);
the molecular sieve catalyst comprises a second carrier and an active component, the second carrier is a small pore molecular sieve material, and the active component is copper in an amount of 2.5-5% of the molecular sieve catalyst or a mixture of platinum and palladium in an amount of 0.1-3% of the molecular sieve catalyst;
the one or more coatings comprise:
a coating layer comprising a uniform mixture of the three-way catalyst and the molecular sieve catalyst; or
a first coating comprising the three-way catalyst and a second coating comprising the molecular sieve catalyst on a surface of the first coating; or
a first segment comprising the three-way catalyst on a former segment of the base body, and a second segment comprising the molecular sieve catalyst on a latter segment of the base body.
2. The integrated catalyst system according to claim 1 , wherein a combined loading amount of the three-way catalyst and the molecular sieve catalyst is 150 g/L-300 g/L, and
a loading amount ratio of the three-way catalyst to the molecular sieve catalyst is (1:3)-(3:1).
3. The integrated catalyst system according to claim 2 , wherein the combined loading amount of the three-way catalyst and the molecular sieve catalyst is 200 g/L-300 g/L, and the loading amount ratio of the three-way catalyst to the molecular sieve catalyst is (1:1)-(2:1).
4. The integrated catalyst system according to claim 1 , wherein in the carrier of the three-way catalyst, a weight ratio of the lanthanum-modified aluminum oxide and the ceria-zirconia solid solution is from 2:5 to 5:2.
5. The integrated catalyst system according to claim 1 , wherein a content of the platinum, the palladium and the rhodium in the three-way catalyst is 80-200 g/ft 3 .
6. The integrated catalyst system according to claim 1 , wherein the carrier of the molecular sieve catalyst is one or both of an aluminosilicophosphate molecular sieve or an aluminosilicate molecular sieve containing a CHA crystal framework structure.
7. The integrated catalyst system according to claim 1 , wherein the one or more coatings comprise the coating layer comprising the uniform mixture of the three-way catalyst and the molecular sieve catalyst.
8. The integrated catalyst system according to claim 1 , wherein the one or more coatings comprise the first coating comprising the three-way catalyst and the second coating comprising the molecular sieve catalyst on the surface of the first coating.
9. The integrated catalyst system according to claim 1 , wherein the one or more coatings comprise the first coating and the second coating.
10. The integrated catalyst system according to claim 9 , wherein the one or more coatings further comprise a third coating comprising the three-way catalyst on the second coating.
11. The integrated catalyst system according to claim 1 , wherein the one or more coatings comprise the first segment comprising the three-way catalyst on the former segment of the base body, and the second segment comprising the molecular sieve catalyst on the latter segment of the base body.
12. The integrated catalyst system according to claim 11 , wherein a height ratio of the first segment and the second segment is 2:1-1:2.
13. The integrated catalyst system according to claim 1 , wherein the active component of the molecular sieve catalyst is copper in an amount of 2.5-3% of the molecular sieve catalyst.
14. The integrated catalyst system according to claim 1 , wherein the active component is the mixture of platinum and palladium in an amount of 0.1-1.0% of the molecular sieve catalyst.
15. The integrated catalyst system according to claim 1 , wherein the content of the platinum, the palladium and the rhodium in the three-way catalyst is 120-180 g/ft 3 .
16. The integrated catalyst system according to claim 15 , wherein the content of the platinum, the palladium and the rhodium in the three-way catalyst is 120-150 g/ft 3 .
17. The integrated catalyst system according to claim 1 , wherein the weight ratio of the platinum, the palladium and the rhodium in the three-way catalyst is 0.3:0.6:0.1.
18. The integrated catalyst system according to claim 1 , wherein the base body comprises a honeycomb ceramic.
19. The integrated catalyst system according to claim 18 , wherein the honeycomb ceramic comprises a cordierite honeycomb ceramic carrier.