High-strength galvanized steel sheet, high strength member, and method for manufacturing the same
A high-strength galvanized steel sheet includes a steel sheet containing a predetermined component element, a mass ratio of a content amount of Si to a content amount of Mn in the steel (Si/Mn) being 0.2 or more, and a steel structure in which an average grain size of inclusions existing in an area extending from a surface to a position of ⅓ of a sheet thickness is 50 μm or less, and an average nearest distance between ones of the inclusions is 20 μm or more; and a galvanized layer provided on a surface of the steel sheet, in which an amount of diffusible hydrogen contained in the steel is less than 0.25 mass ppm, oxides containing predetermined elements in an outer layer portion of the steel sheet account for 0.010 g/m 2 or more per one surface, and a tensile strength is 1100 MPa or more.
1. A high-strength galvanized steel sheet comprising:
a steel sheet having a chemical composition containing a steel composition containing, in mass %,
C: 0.08% or more and 0.20% or less,
Si: less than 2.0%,
Mn: 1.5% or more and 3.5% or less,
P: 0.02% or less,
S: 0.002% or less,
Al: 0.10% or less, and
N: 0.006% or less,
a mass ratio of a content of Si to a content of Mn in the steel (Si/Mn) being 0.2 or more, and the balance: Fe and incidental impurities, and
a steel structure in which an average grain size of inclusions containing at least one of Al, Si, Mg, and Ca and existing in an area extending from a surface to a position of ⅓ of a sheet thickness is 50 μm or less, and an average nearest distance between the inclusions is 20 μm or more; and
a galvanized layer provided on a surface of the steel sheet and having a coating weight per one surface of 20 g/m 2 or more and 120 g/m 2 or less,
wherein an amount of diffusible hydrogen contained in the steel sheet is less than 0.25 mass ppm,
oxides containing at least one or more elements selected from Fe, Si, Mn, Al, P, B, Nb, Ti, Cr, Mo, V, Cu, and Ni and existing in an outer layer portion of the steel sheet within 100 μm from a surface of an underlying steel sheet immediately below the galvanized layer account for 0.010 g/m 2 or more per one surface, and
a tensile strength is 1100 MPa or more,
and wherein the steel structure contains 30% or more and 85% or less of martensite, 60% or less (including 0%) of ferrite, 15% or less (including 0%) of bainite, and less than 5% (including 0%) of retained austenite in terms of area ratio, and
an average grain size of ferrite is 15 μm or less.
2. The high-strength galvanized steel sheet according to claim 1 , wherein the chemical composition further contains, in mass %, at least one of (1) to (5) below,
(1) one or more of Ti, Nb, V, and Zr: 0.005% or more and 0.1% or less in total,
(2) one or more of Mo, Cr, Cu, and Ni: 0.01% or more and 0.5% or less in total,
(3) B: 0.0003% or more and 0.005% or less,
(4) at least one of Sb: 0.001% or more and 0.1% or less and Sn: 0.001% or more and 0.1% or less, and
(5) Ca: 0.0005% or less.
3. A method for manufacturing the high-strength galvanized steel sheet according to claim 1 , comprising: a casting step of casting steel having the chemical composition under a condition where a flow velocity of molten steel at a solidification interface in vicinity of a meniscus of a casting mold is 16 cm/s or more, and producing a steel raw material;
a hot rolling step of hot rolling the steel raw material after the casting step, thereby producing a steel sheet;
a pickling step of pickling the steel sheet after the hot rolling step;
a cold rolling step of cold rolling the steel sheet after the pickling step at a rolling reduction ratio of 20% or more and 80% or less;
an annealing step of heating the steel sheet after the cold rolling step in a continuous annealing line at an annealing temperature of 740° C. or more and (Ac3+20)° C. or less in an atmosphere in a furnace of the continuous annealing line in which a hydrogen concentration in a temperature region of 500° C. or more is more than 0 vol % and 12 vol % or less and a dew-point temperature in a temperature region of 740° C. or more is −25° C. or more, and then performing cooling at an average cooling rate of 3° C./s or more from the annealing temperature to at least 600° C.; and
a plating step of subjecting the steel sheet after the annealing step to plating treatment, and after the plating treatment, performing cooling at an average cooling rate of 3° C./s or more through a temperature region of 450° C. to 250° C.
4. A method for manufacturing the high-strength galvanized steel sheet according to claim 2 , comprising: a casting step of casting steel having the chemical composition under a condition where a flow velocity of molten steel at a solidification interface in vicinity of a meniscus of a casting mold is 16 cm/s or more, and producing a steel raw material;
a hot rolling step of hot rolling the steel raw material after the casting step, thereby producing a steel sheet;
a pickling step of pickling the steel sheet after the hot rolling step;
a cold rolling step of cold rolling the steel sheet after the pickling step at a rolling reduction ratio of 20% or more and 80% or less;
an annealing step of heating the steel sheet after the cold rolling step in a continuous annealing line at an annealing temperature of 740° C. or more and (Ac3+20) ° C. or less in an atmosphere in a furnace of the continuous annealing line in which a hydrogen concentration in a temperature region of 500° C. or more is more than 0 vol % and 12 vol % or less and a dew-point temperature in a temperature region of 740° C. or more is −25° C. or more, and then performing cooling at an average cooling rate of 3° C./s or more from the annealing temperature to at least 600° C.; and
a plating step of subjecting the steel sheet after the annealing step to plating treatment, and after the plating treatment, performing cooling at an average cooling rate of 3° C./s or more through a temperature region of 450° C. to 250° C.
5. The method according to claim 3 , further comprising at least one of (1) and (2) below,
(1) after the plating step, a width trimming step of performing width trimming, and
(2) after the annealing step or after the plating step, a post-treatment step of performing heating in a temperature region of 50 to 400° C. for 30 seconds or more in an atmosphere with a hydrogen concentration of 5 vol % or less and a dew-point temperature of 50° C. or less.
6. The method according to claim 4 , further comprising at least one of (1) and (2) below,
(1) after the plating step, a width trimming step of performing width trimming, and
(2) after the annealing step or after the plating step, a post-treatment step of performing heating in a temperature region of 50 to 400° C. for 30 seconds or more in an atmosphere with a hydrogen concentration of 5 vol % or less and a dew-point temperature of 50° C. or less.
7. The method according to claim 3 , wherein alloying treatment is performed immediately after the plating treatment in the plating step.
8. The method according to claim 4 , wherein alloying treatment is performed immediately after the plating treatment in the plating step.
9. The method according to claim 5 , wherein alloying treatment is performed immediately after the plating treatment in the plating step.
10. The method according to claim 6 , wherein alloying treatment is performed immediately after the plating treatment in the plating step.
11. A high strength member, obtained by subjecting the high-strength galvanized steel sheet according to claim 1 to at least either one of forming and welding.
12. A high strength member, obtained by subjecting the high-strength galvanized steel sheet according to claim 2 to at least either one of forming and welding.
13. A method for manufacturing a high strength member, comprising a step of performing at least either one of forming and welding on a high-strength galvanized steel sheet manufactured by the method according to claim 3 .
14. A method for manufacturing a high strength member, comprising a step of performing at least either one of forming and welding on a high-strength galvanized steel sheet manufactured by the method according to claim 4 .
15. A method for manufacturing a high strength member, comprising a step of performing at least either one of forming and welding on a high-strength galvanized steel sheet manufactured by the method according to claim 5 .
16. A method for manufacturing a high strength member, comprising a step of performing at least either one of forming and welding on a high-strength galvanized steel sheet manufactured by the method according to claim 6 .
17. A method for manufacturing a high strength member, comprising a step of performing at least either one of forming and welding on a high-strength galvanized steel sheet manufactured by the method according to claim 7 .
18. A method for manufacturing a high strength member, comprising a step of performing at least either one of forming and welding on a high-strength galvanized steel sheet manufactured by the method according to claim 8 .
19. A method for manufacturing a high strength member, comprising a step of performing at least either one of forming and welding on a high-strength galvanized steel sheet manufactured by the method according to claim 9 .
20. A method for manufacturing a high strength member, comprising a step of performing at least either one of forming and welding on a high-strength galvanized steel sheet manufactured by the method according to claim 10 .