Sealing material
The present invention relates to composite sealing materials for a gasket. The gaskets are useful in solid oxide fuel/electrolyser cells (SOFC and SOEC). The fuel cell gaskets contain sealing material based upon chemically exfoliated vermiculite that has improved corrosion resistance. The sealing material comprises chemically exfoliated vermiculite; filler; and insoluble carbonate.
1. A gasket for sealing two mating surfaces of a solid oxide cell, the gasket comprising a core layer interposed between a first and a second coating layer, wherein the core layer comprises a composite sealing material comprising:
(a) a chemically exfoliated vermiculite (“CEV”);
(b) a filler; and
(c) an insoluble carbonate, wherein the insoluble carbonate has a solubility in water of less than 0.1 g/ml at 25° C.;
wherein the coating layers each comprise glass, glass-ceramic, and/or ceramic material, and wherein the coating layers have a softening temperature in the range of 500° C. to 950° C.
2. The gasket according to claim 1 , wherein the composite sealing material is in the form of a sheet or foil.
3. The gasket according to claim 1 , wherein the composite sealing material comprises 1-15% w/w insoluble carbonate.
4. The gasket according to claim 1 , wherein the CEV provides up to 100% w/w of a total exfoliated vermiculite in the composite sealing material.
5. The gasket according to claim 1 , wherein a level of the CEV in the composite sealing material is at least 25% w/w.
6. The gasket according to claim 1 , wherein the filler is one or more inert fillers.
7. The gasket according to claim 1 , wherein a level of the filler in the composite sealing material is at least 25% w/w.
8. The gasket according to claim 1 , wherein the CEV, filler, and insoluble carbonate are intimately mixed in the composite sealing material and evenly distributed throughout the composite sealing material so that they form a generally homogenous mixture.
9. The gasket according to claim 1 , wherein the composite sealing material has a density prior to use of 1.5-2.2 g/cm 3 .
10. The gasket according to claim 1 , wherein the composite sealing material is compressible; and wherein an uncompressed thickness of the sealing material is in the range of 10-2000 μm.
11. The gasket according to claim 1 , wherein the insoluble carbonate is selected from a group II carbonate.
12. The gasket according to claim 11 , wherein the group II carbonate is selected from at least one of calcium carbonate or strontium carbonate.
13. The gasket according to claim 11 , wherein the group II carbonate is calcium carbonate.
14. The gasket according to claim 1 , wherein the filler does not comprise an insoluble carbonate.
15. The gasket according to claim 1 , wherein the CEV is not modified CEV comprising water resistance enhancing monovalent cations.
16. The gasket of claim 1 , wherein the solid oxide cell is configured to be operable at a temperature above 500° C.
17. The gasket of claim 1 , wherein the solid oxide cell is configured to be operable at a temperature above 600° C.
18. The gasket according to claim 1 , wherein the coating layers each comprise glass or glass-ceramic material.
19. The gasket according to claim 1 , wherein the coating layers each comprise glass material.
20. A solid oxide cell or a solid oxide cell component comprising one or more gaskets according to claim 1 .
21. A process for sealing a solid oxide cell component comprising incorporating at least one gasket according to claim 1 into the solid oxide cell component.