IP Library › Granted Patent US 12,584,015
Granted Patent B2
US 12,584,015 · App. 17/047,280 · Granted Mar 24, 2026

Polyimide resin composition

Inventors: Yuuki Sato (Kanagawa, JP); Atsushi Sakai (Kanagawa, JP)
Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
C08L79/08C08G73/1082C08K7/14C08K9/04
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Quick Facts
Patent No.
US 12,584,015
App. No.
17/047,280
Granted
Mar 24, 2026
Kind
B2
Abstract

A polyimide resin composition obtained by blending a polyimide resin (A) and glass fiber (B), the polyimide resin (A) containing a repeating structural unit represented by the following formula (1) and a repeating structural unit represented by the following formula (2), a content ratio of the repeating structural unit of the formula (1) with respect to the total of the repeating structural unit of the formula (1) and the repeating structural unit of the formula (2) being 20 to 70 mol %, wherein R 1 represents a divalent group having from 6 to 22 carbon atoms containing at least one alicyclic hydrocarbon structure; R 2 represents a divalent chain aliphatic group having from 5 to 16 carbon atoms; and X 1 and X 2 each independently represent a tetravalent group having from 6 to 22 carbon atoms containing at least one aromatic ring.

Claims (25)

1 . A polyimide resin composition, comprising:

a glass fiber; and

a polyimide resin mixed with the glass fiber and comprising a repeating structural unit of formula (1) and a repeating structural unit of formula (2),

wherein a content ratio of the repeating structural unit of the formula (1) with respect to the total of the repeating structural unit of the formula (1) and the repeating structural unit of the formula (2) is 25 mol % or more and less than 40 mol %, and the formula (1) and the formula (2) are

where R 1 is a divalent group of formula (R1-3), R 2 is a divalent chain aliphatic group having from 8 to 10 carbon atoms, X 1 and X 2 are a tetravalent group of formula (X-5),

wherein an amount of the glass fiber mixed in the polyimide resin composition is in a range of 30 to 65 mass % relative to a total mass of the polyimide resin composition,

wherein an average fiber length of the glass fiber is 3 to 6 mm, and

wherein the glass fiber is surface-treated with at least one selected from the group consisting of a urethane-based sizing agent and a urethane/epoxy-based sizing agent.

2 . The polyimide resin composition according to claim 1 , wherein the glass fiber is surface-treated with a urethane-based sizing agent.

3 . The polyimide resin composition according to claim 1 , wherein an inorganic filler other than the glass fiber is further mixed.

4 . The polyimide resin composition according to claim 3 , wherein an amount of the inorganic filler mixed is 0.05 to 15 mass % relative to a total mass of the polyimide resin composition.

5 . A molded article, comprising:

the polyimide resin composition of claim 1 .

6 . The polyimide resin composition according to claim 1 , wherein the amount of the glass fiber mixed in the polyimide resin composition is 50 to 65 mass % relative to a total mass of the polyimide resin composition.

7 . The polyimide resin composition according to claim 2 , wherein an inorganic filler other than the glass fiber is further mixed.

8 . The polyimide resin composition according to claim 7 , wherein an amount of the inorganic filler mixed is 0.05 to 15 mass % relative to a total mass of the polyimide resin composition.

9 . A molded article, comprising:

the polyimide resin composition of claim 2 .

10 . The polyimide resin composition according to claim 2 , wherein the amount of the glass fiber mixed in the polyimide resin composition is 50 to 65 mass % relative to a total mass of the polyimide resin composition.

11 . A molded article, comprising:

the polyimide resin composition of claim 3 .

12 . The polyimide resin composition according to claim 3 , wherein the amount of the glass fiber mixed in the polyimide resin composition is 50 to 65 mass % relative to a total mass of the polyimide resin composition.

13 . A molded article, comprising:

the polyimide resin composition of claim 6 .

14 . The polyimide resin composition according to claim 4 , wherein the amount of the glass fiber mixed in the polyimide resin composition is 50 to 65 mass % relative to a total mass of the polyimide resin composition.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 14, 2020
From: SATO, YUUKI; SAKAI, ATSUSHI
To: MITSUBISHI GAS CHEMICAL COMPANY, INC.
Reel/Frame 054045/0571 →
Priority Claims (1)
JP 2018-095744 · May 17, 2018 · national
Continuity (1)
Related Publication 20210139701A1 · May 13, 2021
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