Multilayer graphite sheet with excellent electromagnetic shielding capability and thermal conductivity and manufacturing method therefor
An embodiment relates to a multilayer graphite sheet with excellent electromagnetic shielding capability and thermal conductivity, and a manufacturing method therefor, wherein the multilayer graphite sheet has a multilayer structure of five or more layers in total and can be manufactured to have a thick thickness of 70 μm or more such that the electromagnetic shielding capability can be significantly improved. In addition, the multilayer graphite sheet is manufactured by graphitizing a hybrid laminate in which heterogeneous materials are mixed such that thermal conductivity and electromagnetic shielding capability can be simultaneously realized at a lower cost, thereby being useful as a thick film sheet which used in various applications such as home appliances and electric vehicles.
1. A multilayer graphite sheet, which comprises a laminate in which a plurality of first graphite layers and a plurality of second graphite layers are alternately laminated in a total of five layers or more, wherein the first graphite layer is denser than the second graphite layer by 1.1 times or more, wherein the multilayer graphite sheet has an apparent density in the range of greater than 1.1 g/cm 3 to 1.8 g/cm 3 ,
wherein a total thickness of the multilayer graphite sheet is 70 μm to 1,000 μm, the first graphite layer having a thickness of 10 μm to 50 μm and the second graphite layer having a thickness of 5 μm to 60 μm, wherein the total thickness is obtained by subjecting the multilayer graphite sheet to a rolling process.
2. The multilayer graphite sheet of claim 1 , wherein the multilayer graphite sheet has an electromagnetic shielding capability of 110 dB or more in the range of 30 MHz to 1,500 MHz and a thermal conductivity of 700 W/m·K to 1,300 W/m·K in the a horizontal direction.
3. The multilayer graphite sheet of claim 1 , wherein the first graphite layer is denser than the second graphite layer by not more than 10 times.
4. The multilayer graphite sheet of claim 1 , wherein the first graphite layer is a surface layers on both sides of the multilayer graphite sheet.
5. The multilayer graphite sheet of claim 1 , wherein the plurality of the first graphite layers comprises 3 to 6 layers and the plurality of the second graphite layers comprises 2 to 5 layers.
6. The multilayer graphite sheet of claim 1 , wherein the first graphite layer has a thickness variation of less than 40 μm, and the second graphite layer has a thickness variation of 40 μm or more.
7. The multilayer graphite sheet of claim 1 , wherein the interface between the first graphite layer and the second graphite layer has a curved shape of a wavy pattern.
8. The multilayer graphite sheet of claim 1 , wherein the first graphite layer comprises a graphitized material of a cured resin, and the second graphite layer comprises a graphitized material of a fibrous substrate.
9. The multilayer graphite sheet of claim 8 , wherein the cured resin comprises a cured material of a composition comprising polyamic acid.
10. The multilayer graphite sheet of claim 8 , wherein the fibrous substrate is a woven, nonwoven, or paper that comprises at least one fiber selected from the group consisting of natural fibers, cellulose based fibers, and synthetic fibers,
wherein the natural fibers comprise cotton, hemp, wool, and silk,
wherein the cellulose based fibers comprise rayon, acetate, and triacetate, and
wherein the synthetic fibers comprise nylon, polyester, polyurethane, polyethylene, polyvinyl chloride, polyfluoroethylene, polyvinyl alcohol, polyacrylic, and polypropylene.
11. A multilayergraphite sheet, which comprises a laminate in which a plurality of first graphite layers and a plurality of second graphite layers are alternately laminated in a total of five layers or more, wherein the first graphite layer is denser than the second graphite layer,
wherein the first graphite layer comprises a graphitized material of a cured resin layer, and the second graphite layer comprises a graphitized material of fibers defining a fibrous substrate,
wherein a total thickness of the multilayer graphite sheet is 70 μm to 1,000 μm, the first graphite layer has a thickness of 10 μm to 50 μm, and the second graphite layer has a thickness of 5 μm to 60 μm.
12. The multilayer graphite sheet of claim 11 , wherein the multilayer graphite sheet has an electromagnetic shielding capability of 110 dB or more in the range of 30 MHz to 1,500 MHz and a thermal conductivity of 700 W/m·K to 1,300 W/·K in a horizontal direction.
13. The multilayer graphite sheet of claim 11 , wherein the first graphite layer is a surface layer on both sides of the multilayer graphite sheet, and
wherein the plurality of first graphite layers is 3 to 6 layers and the plurality of second graphite layers is 2 to 5 layers.
14. The multilayer graphite sheet of claim 11 , wherein the multilayer graphite sheet is a rolled sheet subjected to a rolling process for obtaining the total thickness and comprises an apparent density in the range of greater than 1.1 g/cm 3 to 1.8 g/cm 3 .
15. The multilayer graphite sheet of claim 11 , wherein the cured resin layer comprises a cured material of a coating composition comprising polyamic acid.
16. The multilayer graphite sheet of claim 11 , wherein the fibrous substrate is a woven, nonwoven, or paper and the fibers are selected from the group consisting of natural fibers, cellulose based fibers, and synthetic fibers,
wherein the natural fibers comprise cotton, hemp, wool, and silk,
wherein the cellulose based fibers comprise rayon, acetate, and triacetate, and
wherein the synthetic fibers comprise nylon, polyester, polyurethane, polyethylene, polyvinyl chloride, polyfluoroethylene, polyvinyl alcohol, polyacrylic, and polypropylene.
17. A multilayer graphite sheet, which comprises a laminate in which a plurality of first graphite layers and a plurality of second graphite layers are alternately laminated in a total of five layers or more, wherein a total thickness of the multilayer graphite sheet is 100 μm to 1,000 μm,
wherein the first graphite layer comprises a graphitized material of a cured resin layer, and the second graphite layer comprises a graphitized material of fibers defining a fibrous substrate, wherein the first graphite layer is denser than the second graphite layer,
wherein the multilayer graphite sheet has an electromagnetic shielding capability of 110 dB or more in the range of 30 MHz to 1,500 MHz and a thermal conductivity of 700 W/·K to 1,300 W/m·K in a horizontal direction.
18. The multilayer graphite sheet of claim 17 , wherein the first graphite layer is a surface layer on both sides of the multilayer graphite sheet, and
wherein the plurality of first graphite layers is 3 to 6 layers and the plurality of second graphite layers is 2 to 5 layers.
19. The multilayer graphite sheet of claim 17 , wherein the multilayer graphite sheet is a rolled sheet subjected to a rolling process for obtaining the total thickness and comprises an apparent density in the range of greater than 1.1 g/cm 3 to 1.8 g/cm 3 .
20. The multilayer graphite sheet of claim 17 , wherein the cured resin layer comprises a cured material of a coating composition comprising polyamic acid, and
wherein the fibrous substrate is a woven, nonwoven, or paper and the fibers are selected from the group consisting of natural fibers, cellulose based fibers, and synthetic fibers,
wherein the natural fibers comprise cotton, hemp, wool, and silk,
wherein the cellulose based fibers comprise rayon, acetate, and triacetate, and
wherein the synthetic fibers comprise nylon, polyester, polyurethane, polyethylene, polyvinyl chloride, polyfluoroethylene, polyvinyl alcohol, polyacrylic, and polypropylene.