Nonwoven with two-part binder system
Disclosed herein is a binder system for nonwoven fiber mats that provides desirable properties to the nonwoven mat including desirable porosity, desirable surface properties e.g., desirable wettability and/or moisture resistance, and enhanced tensile strength. The system includes a two-part binder that includes (1) a formaldehyde-free carbohydrate-based binder and (2) a formaldehyde-free hydrophobic acrylic-based hinder.
1. A nonwoven fiber mat comprising:
randomly oriented fibers; and
a two-part binder system applied to at least a portion of the randomly oriented fibers, wherein the binder system comprises:
a formaldehyde-free carbohydrate-based binder, and
a formaldehyde-free hydrophobic acrylic-based binder,
wherein the formaldehyde-free hydrophobic acrylic-based binder is applied over the formaldehyde-free carbohydrate-based binder,
and wherein the formaldehyde-free acrylic-based binder is impregnated within the nonwoven fiber mat.
2. The nonwoven fiber mat of claim 1 , wherein the mat has a basis weight of about 0.012 to about 0.018 lb/ft 2 (about 60 to about 88 gsm).
3. The nonwoven fiber mat of claim 1 , wherein the nonwoven fiber mat comprises from about 10% to about 30% by weight solids of the two-part binder system based on the total weight of the nonwoven fiber mat.
4. The nonwoven fiber mat of claim 1 , wherein the carbohydrate-based binder comprises a carbohydrate and a crosslinking agent.
5. The nonwoven fiber mat of claim 4 , wherein the carbohydrate comprises a polysaccharide having a dextrose equivalence of 2 to 20.
6. The nonwoven fiber mat of claim 4 , wherein the carbohydrate comprises a water soluble polysaccharide.
7. The nonwoven fiber mat of claim 4 , wherein the carbohydrate comprises maltodextrin, dextrin, starch, modified starch, starch derivative, or combinations thereof.
8. The nonwoven fiber mat of claim 4 , wherein the carbohydrate-based binder comprises from about 30% to about 60% by weight solids of carbohydrate.
9. The nonwoven fiber mat of claim 4 , wherein the crosslinking agent comprises a polycarboxylic acid, a salt of polycarboxylic acid, an anhydride, a polyacrylic acid, a salt of polyacrylic acid, a polyacrylic acid-based resin, or combinations thereof.
10. The nonwoven fiber mat of claim 4 , wherein the carbohydrate-based binder further comprises a coupling agent.
11. The nonwoven fiber mat of claim 1 , wherein the acrylic-based binder has acrylic and/or acrylonitrile functionality.
12. The nonwoven fiber mat of claim 1 , wherein the acrylic-based binder is applied as an emulsion or latex.
13. The nonwoven fiber mat of claim 1 , wherein the hydrophobic acrylic-based binder has a glass transition temperature (Tg) of greater than 20° C.
14. The nonwoven fiber mat of claim 1 , wherein the randomly oriented fibers comprise glass fibers, synthetic polymer fibers, natural fibers, or combinations thereof.
15. The nonwoven fiber mat of claim 1 , wherein the mat has a Frazier permeability of about 690 to about 710 CFM (about 19.5 to about 20.1 m 3 /min).
16. A facer for a construction board comprising the nonwoven fiber mat of claim 1 and a facer coating applied to at least a portion of the nonwoven fiber mat, when the facer has a basis weight of about 0.05 to about 0.08 lb/ft 2 (about 244 to about 391 gsm) and about 10% to about 30% by weight solids of the two-part binder system and facer coating based on the total weight of the facer, the facer has an average Gurley gas permeability of about 1400 s to about 2150 s.
17. The facer of claim 16 , wherein the facer has a basis weight of about 0.065 lb/ft 2 (about 317 gsm).
18. A foam insulation board comprising at least one facer of claim 16 disposed adjacent to a foam core.
19. The foam insulation board of claim 18 , wherein the foam core is selected from the group consisting of polyurethane, polyisocyanurate, polyurethane modified polyisocyanurate, and phenolic resin.
20. A gypsum board comprising at least one facer of claim 16 disposed adjacent to a gypsum core.