Granted Patent B2

US 12,605,691 · App. 17/060,293 · Granted Apr 21, 2026

Inventors: James A. Mennell (Dellwood, MN); Daniel J. Despen (Oakdale, MN); David Reamer (Oakdale, MN)

Assignee: Carbon Technology Holdings, LLC

B01J20/20B01J20/3078C01B32/324C01B32/336C01B32/39C01B32/50G06Q10/04B01J2219/00013B01J2219/24C10B49/02C10B53/02Y02C20/40Y02E50/10Y02E50/30Y02P20/133Y02P20/145

Abstract

Claims (22)

1 . A method of retrofitting a biomass host plant, the method comprising:

(i) installing a reactor system within or adjacent to the host plant, wherein the host plant receives a feedstock comprising biomass and produces a primary product and a co-product, wherein the feedstock is not pyrolyzed in the reactor system at the host plant;

(ii) conveying, to the reactor system, a co-product, wherein the co-product comprises carbon, wherein the co-product is obtained from the biomass host plant and arises from operation of the biomass host plant, and wherein the co-product is selected from the group consisting of wood waste, sawdust, fines, bark, distillers grains, residual solids from fermentation, lignocellulosic residues, lignin, carbon-containing ash, and combinations thereof;

(iii) pyrolyzing, using the reactor system, the co-product, thereby generating a carbon-containing biogenic reagent and pyrolysis off-gas;

(iv) oxidizing the pyrolysis off-gas, thereby generating CO, CO 2 , and energy; and

(v) recycling and utilizing the energy in the host plant.

2 . The method of claim 1 , further comprising recycling and utilizing the CO in the reactor system.

3 . The method of claim 1 , wherein the host plant is selected from the group consisting of a saw mill, a pulp mill, a pulp and paper plant, a corn wet mill, a corn dry mill, a corn ethanol plant, a cellulosic ethanol plant, a sugarcane ethanol plant, a grain processing plant, a sugar production facility, a food plant, a nut processing facility, a fruit processing facility, a vegetable processing facility, a cereal processing facility, and a beverage production facility.

4 . The method of claim 1 , wherein the biomass is selected from the group consisting of softwood chips, hardwood chips, timber harvesting residues, tree branches, tree stumps, leaves, bark, sawdust, corn, corn stover, wheat, wheat straw, rice, rice straw, sugarcane, sugarcane bagasse, sugarcane straw, energy cane, sugar beets, sugar beet pulp, sunflowers, sorghum, canola, algae, miscanthus, alfalfa, switchgrass, fruits, fruit shells, fruit stalks, fruit peels, fruit pits, vegetables, vegetable shells, vegetable stalks, vegetable peels, vegetable pits, grape pumice, almond shells, pecan shells, coconut shells, coffee grounds, food waste, commercial waste, grass pellets, hay pellets, wood pellets, cardboard, paper, paper pulp, paper packaging, paper trimmings, food packaging, lignin, animal manure, municipal solid waste, municipal sewage, and combinations thereof.

5 . The method of claim 1 , further comprising performing, using the reactor system, a continuous process for producing the biogenic reagent, the continuous process comprising:

(a) mechanically contacting, in a heated reaction zone, the co-product with a vapor stream comprising a substantially inert gas and at least one of water or carbon dioxide, thereby generating solids, condensable vapors, and non-condensable gases, wherein the condensable vapors and the non-condensable gases enter the vapor stream;

(b) removing at least a portion of the vapor stream from the reaction zone, thereby generating a separated vapor stream;

(c) recycling at least a portion of the separated vapor stream, or a thermally treated form thereof, to contact the co-product prior to step (b) and/or to convey to a gas inlet of the reaction zone(s); and

(d) recovering at least a portion of the solids from the heated reaction zone as the carbon-containing biogenic reagent.

6 . The method of claim 1 , wherein utilizing the energy in the host plant comprises using the energy to dry the feedstock, the co-product, and/or the primary product from the host plant.

7 . The method of claim 1 , wherein utilizing the energy in the host plant comprises producing steam and/or electricity for use at the host plant.

8 . The method of claim 1 , wherein recycling and utilizing the energy in the host plant comprises using the energy as pyrolysis heat.

9 . The method of claim 1 , wherein the reactor system has a throughput capacity from about 10 ton/day to about 1000 ton/day on a dry basis.

10 . The method of claim 9 , wherein the reactor system has a throughput capacity from about 50 ton/day to about 500 ton/day on a dry basis.

11 . The method of claim 1 , wherein step (iv) is carried out in an oxidation unit that has an energy-generation capacity from about 1 million Btu/hour to about 50 million Btu/hour.

12 . The method of claim 11 , wherein the oxidation unit has an energy-generation capacity from about 10 million Btu/hour to about 20 million Btu/hour.

13 . The method of claim 1 , wherein the primary product is not pyrolyzed in the reactor system at the host plant.

Assignments (7)

Continuity (4)

References Cited (400)