Method for recovering active metal of lithium secondary battery
A method for recovering an active metal of a lithium secondary battery according to an embodiment of the present application whereby a used lithium-containing mixture is prepared, and the used lithium-containing mixture is treated with a hydrogen reduction to prepare a preliminary precursor mixture. The preliminary precursor mixture is washed with water to generate a lithium precursor including lithium hydroxide. Lithium hydroxide can be obtained by the washing treatment with high purity.
1 . A method for recovering an active metal of a lithium secondary battery, the method comprising:
preparing a used lithium-containing mixture;
treating the used lithium-containing mixture with a hydrogen reduction to prepare a preliminary precursor mixture; and
washing the preliminary precursor mixture with water to generate a lithium precursor including lithium hydroxide, wherein the preliminary precursor mixture includes a preliminary lithium precursor and a transition metal-containing product, and the preliminary lithium precursor includes lithium hydroxide,
wherein the washing with water is performed in a carbon dioxide (CO 2 )-free atmosphere by purging with a CO 2 -deficient gas-so that generation of lithium carbonate is prevented from the lithium hydroxide in the preliminary lithium precursor.
2 . The method of claim 1 , wherein the preparing the used lithium-containing mixture comprises preparing a cathode active material mixture from a used lithium secondary battery.
3 . The method of claim 2 , wherein the preparing the cathode active material mixture comprises:
separating a cathode including a cathode current collector, a cathode active material, a binder and a conductive agent from the used lithium secondary battery; and
removing the cathode current collector by grinding the separated cathode or treating the separated cathode with an organic solvent.
4 . The method of claim 1 , wherein the hydrogen reduction is performed through a fluidized bed reactor utilizing a hydrogen gas.
5 . The method of claim 1 , wherein the preliminary lithium precursor further includes lithium oxide and lithium carbonate.
6 . The method of claim 5 , wherein lithium oxide and lithium carbonate included in the preliminary lithium precursor are removed by the washing with water.
7 . The method of claim 6 , wherein an aqueous lithium hydroxide solution is generated and the transition metal-containing product is precipitated by the washing with water.
8 . The method of claim 7 , further comprising treating the precipitated transition metal-containing product with an acidic solution to regenerate a transition metal precursor.
9 . The method of claim 1 , wherein the CO 2 -deficient gas is nitrogen.
10 . The method of claim 1 , wherein the lithium precursor consists of lithium hydroxide.