Polybutadiene, production and use thereof
The invention relates to polybutadiene, which contains the monomer units derived from 1,3-butadiene having a vinyl double bond in a proportion of 25 to 75 mole percent, having a trans-double bond in a proportion of 0 to 10 mole percent and a cis-double bond in a proportion of 25 to 75 mole percent, wherein the totality of the monomer units (A), (B) and (C) is supplemented to 100 mole percent, and which is characterized in that it has a number-average mole mass of 1,000 to 3,000 g/mole. The invention further relates to a method for producing polybutadienes, the use of the polybutadiene according to the invention and compositions containing polybutadiene according to the invention.
1. A method for preparing a polybutadiene comprising monomer units derived from 1,3-butadiene
wherein the proportion of monomer units of the formula (A) in the entirety of the monomer units derived from 1,3-butadiene present in the polybutadiene is 25 to 75 mole percent, the proportion of units of the formula (B) in the entirety of the monomer units derived from 1,3-butadiene present in the polybutadiene is from 2 to 6 mole percent and the proportion of monomer units of the formula (C) in the entirety of the monomer units derived from 1,3-butadiene present in the polybutadiene is 25 to 75 mole percent, wherein the entirety of the monomer units (A), (B) and (C) add up to 100 mole percent, and the polybutadiene has a number-average molar mass of 1000 to 3000 g/mol,
the method comprising the step of
polymerizing 1,3-butadiene in the presence of a solvent and a catalyst system comprising a) a cobalt compound, b) an organoaluminium compound, c) an organophosphorus compound and d) water, wherein a mixture of catalyst system and solvent is initially charged and the 1,3-butadiene is metered into this mixture,
wherein the polymerization is carried out at a pressure of from 2 to 7 bar.
2. The method according to claim 1 , wherein the polymerization is carried out at a pressure of from 3 to 7 bar.
3. The method according to claim 1 , wherein the polymerization is carried out at a temperature of the reaction mixture of from 20 to 60° C.
4. The method according to claim 1 , wherein the cobalt compound is cobalt 2-ethylhexanoate.
5. The method according to claim 1 , wherein the organophosphorus compound is tris(2,4-di-tert-butylphenyl) phosphite or tris(ortho-phenylphenyl) phosphite.
6. The method according to claim 1 , wherein the organoaluminium compound is ethylaluminium sesquichloride or diethylaluminium chloride.
7. The method according to claim 1 , wherein the molar ratio of cobalt compound to total amount of 1,3-butadiene used is from 1:2500 to 1:15,000.
8. The method according to claim 1 , wherein the cobalt compound is cobalt 2-ethylhexanoate.
9. The method according to claim 1 , wherein the organophosphorus compound is tris(2,4-di-tert-butylphenyl) phosphite or tris(ortho-phenylphenyl) phosphite.
10. The method according to claim 3 , wherein the organoaluminium compound is ethylaluminium sesquichloride or diethylaluminium chloride.
11. The method according to claim 3 , wherein the molar ratio of cobalt compound to total amount of 1,3-butadiene is from 1:2500 to 1:15,000.
12. The method according to claim 1 , wherein the polybutadiene has a viscosity of 2000 to 8000 mPa s at 20° C.
13. The method according to claim 1 , wherein the polybutadiene has a dispersity of 2.1 to 3.0.
14. The method according to claim 1 , wherein the proportion of monomer units of the formula (A) in the entirety of the monomer units derived from 1,3-butadiene present in the polybutadiene is 50 to 65 mole percent, the proportion of units of the formula (B) in the entirety of the monomer units derived from 1,3-butadiene present in the polybutadiene is 2 to 6 mole percent and the proportion of monomer units of the formula (C) in the entirety of the monomer units derived from 1,3-butadiene present in the polybutadiene is 25 to 40 mole percent, wherein the entirety of the monomer units (A), (B) and (C) add up to 100 mole percent, and the polybutadiene has a number-average molar mass of 1200 to 1700 g/mol.
15. A product comprising the polybutadiene according to the method of claim 1 wherein the product is selected from the group consisting of rubber, synthetic rubber, tyres, adhesive formulations, coating compositions, flexographic printing plates, coating agents, coating agent components, and plasticizers.
16. A composition comprising the polybutadiene according to the method of claim 1 or conversion products of polybutadiene with other compounds.
17. The composition according to claim 16 , wherein the proportion of the polybutadiene, which are present in the composition or were used for preparing the conversion products, based on the composition, is from 0.1 to 90% by weight.
18. The method according to claim 1 , wherein said polybutadiene has a dispersity of 2.1 to 3.0.
19. The composition according to claim 16 , wherein the polybutadiene has a viscosity of 2000 to 8000 mPa s at 20° C.
20. The composition according to claim 16 , wherein the polybutadiene has a dispersity of 2.1 to 3.0.