Positive active material for rechargeable lithium battery, preparing method thereof and rechargeable lithium battery comprising positive electrode including positive active material
A positive active material for a rechargeable lithium battery includes a first positive active material including a secondary particle including at least two agglomerated primary particles, where at least one part of the primary particles has a radial arrangement structure, as well as a second positive active material having a monolith structure. The first and second positive active materials may both include nickel-based positive active materials. A method of preparing the positive active material, and a rechargeable lithium battery including a positive electrode including the positive active material are also provided.
1. A method of preparing a positive active material for a rechargeable lithium battery, comprising:
subjecting a first precursor to a first heat-treatment in an oxidizing gas atmosphere to obtain a first nickel-based oxide,
subjecting a second precursor to a second heat-treatment in an oxidizing gas atmosphere to obtain a second nickel-based oxide,
mixing the first nickel-based oxide and the second nickel-based oxide to yield a mixture, and subjecting the mixture to a third heat-treatment at a temperature of 800° C. to 1000° C. in an oxidizing gas atmosphere to obtain a positive active material comprising a first positive active material and a second positive active material,
wherein the second nickel-based oxide comprises particles having a monolith structure.
2. The method of claim 1 , wherein obtaining the second nickel-based oxide comprises pulverizing a resulting material obtained after subjecting the second precursor to the second heat-treatment in an oxidizing gas atmosphere.
3. A method of preparing a positive active material for a rechargeable lithium battery, comprising:
subjecting a first precursor to a first heat-treatment in an oxidizing gas atmosphere to obtain a first nickel-based oxide,
subjecting a second precursor to a second heat-treatment in an oxidizing gas atmosphere to obtain a second nickel-based oxide,
mixing the first nickel-based oxide and the second nickel-based oxide to yield a mixture, and subjecting the mixture to a third heat-treatment in an oxidizing gas atmosphere to obtain a positive active material comprising a first positive active material and a second positive active material,
wherein the second nickel-based oxide comprises particles having a monolith structure, and
wherein the second precursor is obtained by mixing a second composite metal hydroxide having a specific surface area of about 1 m 2 /g to about 30 m 2 /g, as measured using a BET method, with a lithium-based material.
4. The method of claim 1 , wherein a mixing ratio of the first nickel-based oxide and the second nickel-based oxide is about 9:1 to about 5:5 based on a weight ratio.