Synthesis of aza-acenes as novel n-type materials for organic electronics
Acenes, such as aza-acenes are attractive materials for organic semiconductors, specifically for n-type materials. There are disclosed new derivatives of acenes that are fabricated using novel synthesis. For example, the disclosed fabrication strategies have allowed for the first time new aza-tetracene and aza-pentacene derivatives. The HOMO and LUMO energy levels of these materials are tunable through appropriate substitution and as predicted, deepened. There are also disclosed organic photosensitive devices comprising at least one aza-acene such as aza-tetracene and aza-pentacene.
1. An organic photosensitive optoelectronic device comprising at least one heterojunction at the interface of at least one donor material and at least one acceptor material, wherein the acceptor material comprises at least one aza-acene;
wherein the aza-acene is a diaza-tetracene selected from 4,10-diphenyl-3,9-diaza-tetracene (DPDAT), 4,8,10,14-tetraphenyl-3,9-diaza-tetracene (TPDAT), 4,10-dichloro-3,9-diaza-tetracene (DCDAT), 8,14-diphenyl-4,10-dichloro-3,9-diaza-tetracene (DPDCDAT), 8,14-diphenyl-4,10-dicyano-3,9-diaza-tetracene (DPDCNDAT), and 4,10-dicyano-3,9-diaza-tetracene (DCNDAT).
2. The device of claim 1 , wherein the diaza-tetracene is DPDCNDAT and the at least one donor material is boron subphthalocyanonine chloride(SubPc).
3. The device of claim 2 having a structure Indium Tin Oxide (ITO)/SubPc/DPDCNDAT/Bathocuproine (BCP)/Al.