Treatment of epoxidized unsaturated isoolefin copolymers
A process for producing a crosslinked polymer involves contacting an epoxidized unsaturated isoolefin copolymer with a catalytic amount of an acid in an absence of a solvent. A process for producing a hydroxylated unsaturated isoolefin copolymer involves contacting an epoxidized unsaturated isoolefin copolymer with a catalytic amount of an acid in an absence of a solvent. A hydroxylated unsaturated isoolefin copolymer having hydroxyl groups in endo configurations may be produced thereby.
1. A hydroxylated unsaturated isoolefin copolymer comprising hydroxyl groups in endo configurations; wherein the copolymer comprises 80 to 97.5 mole percent isoolefin monomer and 2.5 to 20 mole percent multiolefin monomer.
2. The copolymer according to claim 1 , wherein the isoolefin monomer comprises isobutene or the at least one multiolefin monomer comprises isoprene.
3. The copolymer of claim 1 , wherein the multiolefin monomer has 4 to 14 carbon atoms.
4. The copolymer of claim 3 , wherein the multiolefin monomer is isoprene, butadiene, 2-methylbutadiene, 2,4-dimethylbutadiene, piperylene, 3-methyl-1,3-pentadiene, 2,4-hexadiene, 2-neopentylbutadiene, 2-methyl-1,5-hexadiene, 2,5-dimethyl-2,4-hexadiene, 2-methyl-1,4-pentadiene, 2-methyl-1,6-heptadiene, cyclopentadiene, methylcyclopentadiene, cyclohexadiene, 1-vyinyl-cyclohexadiene, or a combination thereof.
5. The copolymer of claim 4 , wherein the isoolefin monomer is isobutene, 2-methyl-1-butene, 3-methyl-1-butene, 2-methyl-2-butene, 4-methyl-1-pentene, or a combination thereof.
6. The copolymer of claim 3 , wherein the isoolefin monomer has 4 to 16 carbon atoms.
7. The copolymer of claim 1 , wherein the isoolefin monomer is present in an amount of 92.5 to 97.5 mole percent, and the multiolefin is present in an amount of 2.5 to 7.5 mole percent, based on the total number of moles of monomer in the copolymer.
8. The copolymer of claim 1 , wherein the copolymer is a random copolymer.
9. The copolymer of claim 1 , wherein the copolymer includes about 0.1% or more endo-OH groups.
10. A compound comprising:
the copolymer of claim 1 ; and
one or more auxiliary materials selected from the group consisting of a reaction accelerator, a vulcanization accelerator, an antioxidant, a foaming agent, an anti-aging agent, a heat stabilizer, a light stabilizer, an ozone stabilizer, a processing aid, a plasticizer, a tackifier, a blowing agent, a dyestuff, a pigment, a wax, an extender, an organic acid, an inhibitor, a metal oxide, an activator, and a filler.
11. A polymer product including the copolymer of claim 1 .
12. A hydroxylated unsaturated isoolefin copolymer comprising hydroxyl groups in endo configuration;
wherein the copolymer comprises an isoolefin monomer and a multiolefin monomer;
wherein the copolymer includes α-methyl styrene, chlorostyrene, cyclopentadiene, or methylcyclopentadiene.
13. The copolymer of claim 12 , wherein the copolymer is a copolymer of isobutylene, isoprene, and para-methyl styrene.
14. A hydroxylated unsaturated isoolefin copolymer comprising hydroxyl groups in endo configuration;
wherein the copolymer comprises an isoolefin monomer and a multiolefin monomer;
wherein the copolymer includes an allylic halide.
15. A hydroxylated unsaturated isoolefin copolymer comprising hydroxyl groups in endo configuration and hydroxyl groups in exo configuration; wherein a ratio of endo-OH to exo-OH in the copolymer is from about 0.1:0.5 to 0.17:0.54.
16. The copolymer according to claim 15 , wherein the isoolefin copolymer comprises repeating units derived from at least one isoolefin monomer and repeating units derived from at least one multiolefin monomer.
17. The copolymer of claim 16 , wherein the isoolefin monomer includes isobutene and the multiolefin monomer includes isoprene.
18. The copolymer of claim 16 , wherein the molar ratio of the isoolefin monomer to the multiolefin monomer is from 80:20 to 97.5:2.5.
19. The copolymer of claim 16 , wherein the isoolefin monomer is present in an amount of 80 to 99.9 mole percent based on the total number of moles of monomer in the copolymer.
20. A polymer product comprising a hydroxylated unsaturated isoolefin copolymer including hydroxyl groups in an endo configuration, wherein the polymer product is a clean cure product for pharmaceutical applications, a transparent material for microelectronic applications, an adhesive, a sealant or a coating.