Multicorrosion protection system for decorative parts with chrome finish
The invention relates to a corrosion protection layer system for metal surfaces, said layer system comprising as the two top most layers: a) a discontinuous nickel-phosphorus layer and b) a chromium layer plated from a trivalent chromium electrolyte solution, as well as to a method of producing such a layer system. The inventive layer system is capable to combine the good corrosion resistance of the nickel-phosphorus layer against sodium chloride with the protective power of the chromium layer from the trivalent plating process against magnesium and calcium salts, especially without the need for any post-treatment.
1. A method for the production of a corrosion protection layer system on metal surfaces, said method comprising the steps of:
a) providing a surface to be protected by a corrosion protection layer system,
b) plating on said surface a-discontinuous nickel-phosphorus layer comprising inorganic solids by an electroplating process from a nickel electrolyte solution, wherein the discontinuous nickel-phosphorus layer comprises micropores and/or microcracks between 100 and 1,000,000 micropores per cm 2 and/or between 10 and 10,000 microcracks per cm, and wherein the nickel-phosphorus layer comprises phosphorus in an amount between 2.0 wt. % and 20.0 wt. %, wherein the total weight of the nickel-phosphorus layer is 100 wt. %; and
c) plating on said layer of step b) a chromium layer rom a trivalent chromium electrolyte solution by an electroplating process.
2. The method according to claim 1 , wherein the nickel electrolyte solution for plating step b) has a pH between 1.0 between 5.0.
3. The method according to claim 2 , wherein the nickel electrolyte solution has a pH between 1.1 and 2.0.
4. The method according to claim 1 , wherein the nickel electrolyte solution for plating step b) has a phosphorus containing additive in a concentration between 0.01 mol/l and 1.0 mol/l.
5. The method according to claim 4 , wherein the nickel electrolyte solution for plating step b) has a phosphorus containing additive in a concentration between 0.05 mol/l and 0.25 mol/l.
6. The method according to claim 4 , wherein the phosphorus containing additive is a hypophosphite or an orthophosphite.
7. The method according to claim 1 , wherein the nickel electrolyte solution for plating step b) comprises insoluble inorganic particles with a mean diameter (d50) of between 0.01 μm and 10.0 μm.
8. The method according to claim 7 , wherein the nickel electrolyte solution for plating step b) comprises insoluble inorganic particles with a mean diameter (d50) of between 0.3 μm and 3.0 μm.
9. The method according to claim 7 , wherein the insoluble inorganic particles in the nickel electrolyte solution for plating step b) are selected from the group consisting of SiO 2 , Al 2 O 3 , TiO 2 , BN, ZrO 2 , talcum, china clay, or mixtures thereof.
10. The method according to claim 1 , wherein the nickel electrolyte solution for plating step b) comprises boric acid.
11. The method according to claim 10 , wherein the boric acid concentration is between 0.1 mol/l and 1.0 mol/l.
12. The method according to claim 11 , wherein the boric acid concentration is between 0.5 mol/l and 0.8 mol/l.
13. The method according to claim 1 , wherein the surface to be protected by a corrosion protection layer system in an exterior automotive part.
14. The method according to claim 1 , wherein said chromium layer plated from a trivalent chromium electrolyte solution is amorphous, crystalline, microporous, or microcracked.