Organic electroluminescence device and polycyclic compound for organic electroluminescence device

1. An organic electroluminescence device, comprising:

a first electrode;

an organic layer on the first electrode; and

a second electrode on the organic layer;

wherein the organic layer comprises a polycyclic compound represented by the following Formula 1:

wherein in Formula 1,

X 1 to X 4 are each independently NR 9 , O or S,

R 1 to R 8 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted boron group, a substituted or unsubstituted silyl group, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group of 2 to 30 carbon atoms for forming a ring,

R 9 is a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group of 2 to 30 carbon atoms for forming a ring, or combined with an adjacent group to form a ring,

a to f are each independently an integer of 0 to 4,

m and n are each independently 0 or 1,

a dotted line represents a bond or a non-bond, and

ring A is represented by any one selected from the following Formula 2-1 to

wherein in Formula 2-1 to Formula 2-3,

* represents a bonding site with a neighboring atom,

X 5 and X 6 are each independently CR 30 R 31 , NR 32 , O or S,

R 30 to R 32 are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group of 2 to 30 carbon atoms for forming a ring, and

R 20 to R 29 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted boron group, a substituted or unsubstituted silyl group, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group of 2 to 30 carbon atoms for forming a ring, and

wherein when ring A is represented by Formula 2-1 or 2-2, at least one selected from m and n is 1.

2. The organic electroluminescence device of claim 1 , wherein the organic layer comprises:

a hole transport region on the first electrode;

an emission layer on the hole transport region; and

an electron transport region on the emission layer.

3. The organic electroluminescence device of claim 2 , wherein the emission layer comprises the polycyclic compound and is to emit delayed fluorescence.

4. The organic electroluminescence device of claim 3 , wherein

the emission layer is a delayed fluorescence emission layer comprising a host and a dopant, and

the dopant is the polycyclic compound.

5. The organic electroluminescence device of claim 3 , wherein the emission layer is a thermally activated delayed fluorescence emission layer to emit blue light.

6. The organic electroluminescence device of claim 2 , wherein the electron transport region comprises:

an electron transport layer on the emission layer; and

an electron injection layer on the electron transport layer, and

wherein the electron transport layer or the electron injection layer comprises the polycyclic compound.

7. The organic electroluminescence device of claim 1 , wherein Formula 2-2 is represented by any one selected from the following Formula 3-1 to Formula 3-4:

wherein in Formula 3-1 to Formula 3-4,

* represents a bonding site with a neighboring atom,

R 30 , R 31 , and R 33 are each independently a hydrogen atom, a deuterium atom, or a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, and

j is an integer of 0 to 5.

8. The organic electroluminescence device of claim 1 , wherein Formula 2-3 is represented by any one selected from the following Formula 4-1 to Formula 4-3:

wherein in Formula 4-1 to Formula 4-3,

* represents a bonding site with a neighboring atom,

R 34 is a hydrogen atom, a deuterium atom, or a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, and

k is an integer of 0 to 5.

9. The organic electroluminescence device of claim 1 , wherein the polycyclic compound represented by Formula 1 is represented by the following Formula 5-1 or Formula 5-2:

wherein in Formula 5-1 and Formula 5-2,

X 1 to X 4 , R 1 to R 8 , R 20 , R 21 , and a to f are the same as respectively defined in connection with Formula 1 and Formula 2-1.

10. The organic electroluminescence device of claim 1 , wherein the polycyclic compound represented by Formula 1 is represented by the following Formula 6-1 or Formula 6-2:

wherein in in Formula 6-1 and Formula 6-2,

X 1 to X 5 , R 1 to R 8 , R 22 to R 25 , and a to f are the same as respectively defined in connection with Formula 1 and Formula 2-2.

11. The organic electroluminescence device of claim 1 , wherein the polycyclic compound represented by Formula 1 is represented by any one selected from the following Formula 7-1 to Formula 7-3:

wherein in Formula 7-1 to Formula 7-3,

X 1 to X 4 , X 6 , R 1 to Ra, R 26 to R 29 , and a to f are the same as respectively defined in Formula 1 and Formula 2-3.

12. The organic electroluminescence device of claim 1 , wherein:

X 1 to X 4 are each independently NR 11 or O; and

R 11 is a substituted or unsubstituted aryl group of 6 to 30 carbon atoms for forming a ring.

13. The organic electroluminescence device of claim 1 , wherein:

X 1 and X 4 are the same; and

X 2 and X 3 are the same.

14. The organic electroluminescence device of claim 1 , wherein the polycyclic compound represented by Formula 1 is any one selected from compounds represented in the following Compound Group 1 to Compound Group 3:

15. A polycyclic compound represented by the following Formula 1:

wherein in Formula 1,

X 1 to X 4 are each independently NR 9 , O or S,

R 1 to R 8 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted boron group, a substituted or unsubstituted silyl group, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group of 2 to 30 carbon atoms for forming a ring,

R 9 is a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group of 2 to 30 carbon atoms for forming a ring, or combined with an adjacent group to form a ring,

a to f are each independently an integer of 0 to 4,

m and n are each independently 0 or 1,

a dotted line represents a bond or a non-bond, and

ring A is represented by any one selected from the following Formula 2-1 to Formula 2-3:

wherein in Formula 2-1 to Formula 2-3,

* represents a bonding site with a neighboring atom,

X 5 and X 6 are each independently CR 30 R 31 , NR 32 , O or S,

R 30 to R 32 are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group of 2 to 30 carbon atoms for forming a ring, and

R 20 to R 29 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted boron group, a substituted or unsubstituted silyl group, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group of 2 to 30 carbon atoms for forming a ring, and

wherein when ring A is represented by Formula 2-1 or 2-2, at least one selected from m and n is 1.

16. The polycyclic compound of claim 15 , wherein Formula 2-2 is represented by any one selected from the following Formula 3-1 to Formula 3-4:

wherein in Formula 3-1 to Formula 3-4,

* represents a bonding site with a neighboring atom,

R 30 , R 31 , and R 33 are each independently a hydrogen atom, a deuterium atom, or a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, and

j is an integer of 0 to 5.

17. The polycyclic compound of claim 15 , wherein Formula 2-3 is represented by any one selected from the following Formula 4-1 to Formula 4-3:

wherein in Formula 4-1 to Formula 4-3,

* represents a bonding site with a neighboring atom,

R 34 is a hydrogen atom, a deuterium atom, or a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, and

k is an integer of 0 to 5.

18. The polycyclic compound of claim 15 , wherein the polycyclic compound represented by Formula 1 is represented by the following Formula 5-1 or Formula 5-2:

wherein in Formula 5-1 and Formula 5-2,

X 1 to X 4 , R 1 to R 8 , R 20 , R 21 , and a to f are the same as respectively defined in connection with Formula 1 and Formula 2-1.

19. The polycyclic compound of claim 15 , wherein the polycyclic compound represented by Formula 1 is represented by the following Formula 6-1 or Formula 6-2:

wherein in Formula 6-1 and Formula 6-2,

X 1 to X 5 , R 1 to R 8 , R 22 to R 25 , and a to f are the same as respectively defined in connection with Formula 1 and Formula 2-2.

20. The polycyclic compound of claim 15 , wherein the polycyclic compound represented by Formula 1 is represented by any one selected from the following Formula 7-1 to Formula 7-3:

wherein in Formula 7-1 to Formula 7-3,

X 1 to X 4 , X 6 , R 1 to R 8 , R 26 to R 29 , and a to f are the same as respectively defined in connection with Formula 1 and Formula 2-3.

21. The polycyclic compound of claim 15 , wherein the polycyclic compound represented by Formula 1 is any one selected from compounds represented in the following Compound Group 1 to Compound Group 3: