NEGATIVE ELECTRODE FOR NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY, AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY
This negative electrode comprises a electrode current collector, a first electrode mixture layer provided on the surface of the electrode current collector, and a second electrode mixture layer provided on the surface of the first electrode mixture layer. The first electrode mixture layer and the second electrode mixture layer have different volume change ratio upon charge and discharge. The first electrode mixture layer has an interface portion in contact with the second electrode mixture layer, and a body portion located nearer to the electrode current collector side than the interface portion. The thickness of the interface portion t satisfies a relationship t≤dg/2 with an average particle size of the graphite particles included in the first electrode mixture layer being dg. The content of an inorganic filler in the interface portion is higher than the content of the inorganic filler included in the body portion.
1 . A negative electrode for a non-aqueous electrolyte secondary battery, comprising:
a negative electrode current collector,
a first negative electrode mixture layer including first graphite particles, the first negative electrode mixture layer being provided on a surface of the negative electrode current collector, and
a second negative electrode mixture layer including second graphite particles, the second negative electrode mixture layer being provided on a surface of the first negative electrode mixture layer; wherein
the first negative electrode mixture layer and the second negative electrode mixture layer have different volume change ratio upon charge and discharge,
the first negative electrode mixture layer has an interface portion in contact with the second negative electrode mixture layer, and a body portion located nearer to the negative electrode current collector side than the interface portion,
a thickness of the interface portion t satisfies a relationship t≤dg/2 with an average particle size of the first graphite particles being dg,
the first negative electrode mixture layer includes an inorganic filler, and
a content of the inorganic filler in the interface portion is higher than a content of the inorganic filler included in the body portion.
2 . The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein
the inorganic filler is ceramic particles, and
an average particle size of the ceramic particles dc satisfies a relationship dc≤dg/10 with the average particle size of the first graphite particles being dg.
3 . The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein
the content of the inorganic filler in the interface portion is 1 mass % to 10 mass % based on a content of the first graphite particles in the first negative electrode mixture layer.
4 . The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein
at least either one of the first negative electrode mixture layer and the second negative electrode mixture layer includes a Si material, and
the first negative electrode mixture layer and the second negative electrode mixture layer have different content of the Si material.
5 . The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein
the first graphite particles and the second graphite particles have different degrees of graphitization.
6 . A non-aqueous electrolyte secondary battery comprising:
the negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 ;
a positive electrode; and
a non-aqueous electrolyte.