Negative electrode for non-aqueous electrolyte secondary battery, and non-aqueous electrolyte secondary battery
View Patent ↗This negative electrode comprises an electrode current collector, and an electrode mixture layer provided on a surface of the electrode current collector. When, with respect to the thickness direction of the electrode mixture layer, a range from the surface on the side of the electrode current collector to 40% of the thickness of the electrode mixture layer is defined as a first region, and a range from the surface on the side opposite to the electrode current collector to 40% of the thickness of the electrode mixture layer is defined as a second region, the first region and the second region have different volume change ratio upon charge and discharge, and the region having the larger volume change ratio upon charge and discharge has a higher content of a solid inorganic filler and a lower content of a hollow inorganic filler than the region having the smaller volume change ratio.
1. A negative electrode for a non-aqueous electrolyte secondary battery, comprising:
a negative electrode current collector; and
a negative electrode mixture layer provided on a surface of the negative electrode current collector, wherein
the negative electrode mixture layer includes at least graphite particles, a solid inorganic filler, and a hollow inorganic filler,
when, with respect to a thickness direction of the negative electrode mixture layer, a range from a surface on a side of the negative electrode current collector to 40% of a thickness of the negative electrode mixture layer is defined as a first region, and a range from a surface on an a side opposite to the negative electrode current collector to 40% of the thickness of the negative electrode mixture layer is defined as a second region,
the first region and the second region have different volume change ratio upon charge and discharge, and
in the first region and the second region, the region having a higher volume change ratio upon charge and discharge has a higher content of the solid inorganic filler and a lower content of the hollow inorganic filler than the region having a lower volume change ratio upon charge and discharge.
2. The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein
the solid inorganic filler and the hollow inorganic filler are ceramic particles.
3. The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein
a total amount of the solid inorganic filler and the hollow inorganic filler included in the first region and the second region is 1 mass % to 10 mass % based on a total amount of the graphite particles included in the first region and the second region.
4. The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein
the negative electrode mixture layer further includes a Si material in at least either one of the first region and the second region, and
the first region and the second region are different in a content of the Si material.
5. The negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein
the graphite particles included in the first region and the graphite particles included in the second region are different in a degree of graphitization.
6. A non-aqueous electrolyte secondary battery comprising:
the negative electrode for a non-aqueous electrolyte secondary battery according to claim 1 ;
a positive electrode; and
a non-aqueous electrolyte.