High conductive passivation layers and method of forming the same during high aspect ratio plasma etching
Disclosed are methods for forming a high aspect ratio (HAR) structure during a HAR etch process in a substrate in a reaction chamber, the method comprising: sequentially or simultaneously exposing the substrate to a vapor of an etchant including a hydrofluorocarbon or fluorocarbon compound and an additive compound, the substrate having a film disposed thereon and a pattered mask layer disposed on the film; activating a plasma to produce an activated hydrofluorocarbon or fluorocarbon compound and an activated additive compound; and allowing an etching reaction to proceed between the film uncovered by the patterned mask layer and the activated hydrofluorocarbon or fluorocarbon compound and the activated additive compound to selectively etch the film from the patterned mask layer, thereby forming the HAR patterned structure.
1. A method for forming a patterned structure during an etch process in a substrate in a reaction chamber, the method comprising:
sequentially or simultaneously exposing the substrate to a vapor of an etchant including C 4 H 2 F 6 , an additional etch gas and an additive compound CH 3 I, the substrate having a film disposed thereon and a patterned mask layer disposed on the film;
activating a plasma to produce an activated C 4 H 2 F 6 , an activated additional etch gas and an activated additive compound; and allowing an etching reaction to proceed between the film uncovered by the patterned mask layer and the activated C 4 H 2 F 6 , the activated additional etch gas and the activated additive compound to selectively etch the film from the patterned mask layer, thereby forming the patterned structure,
wherein the additional etch gas is selected from the group consisting of cC 4 F 8 , C 4 F 8 , cC 5 F 8 , C 5 F 8 , C 4 F 6 , CF 4 , CH 3 F, CF 3 H, CH 2 F 2 , C 3 HF 7 , C 3 F 6 , C 3 H 2 F 6 , C 3 H 2 F 4 , C 3 H 3 F 5 , C 4 HF 7 , C 5 HF 9 , C 3 F 8 , CF 3 I, C 2 F 3 I, C 2 F 5 I, 1-Iodoheptafluoropropane (1-C 3 F 7 I), 2-Iodoheptafluoropropane (2-C 3 F 7 I), COS, FNO, F—C═N, CS 2 , SO 2 , SF 6 , trans-1,1,1,4,4,4-hexafluoro-2-butene (trans-C 4 H 2 F 6 ), cis-1,1,1,4,4,4-hexafluoro-2-butene (cis-C 4 H 2 F 6 ), hexafluoroisobutene (C 4 H 2 F 6 ), trans-1,1,2,2,3,4-hexafluorocyclobutane (trans-C 4 H 2 F 6 ), 1,1,2,2,3-pentafluorocyclobutane (C 4 H 3 F 5 ), 1,1,2,2-tetrafluorocyclobutane (C 4 H 4 F 4 ), and cis-1,1,2,2,3,4-hexafluorocyclobutane (cis-C 4 H 2 F 6 ), and combinations thereof.
2. The method of claim 1 , further comprising the step of introducing an oxidizer into the reaction chamber, wherein the oxidizer is selected from O 2 , O 3 , CO, CO 2 , NO, N 2 O, NO 2 , H 2 O, H 2 O 2 , COS, SO 2 and combinations thereof.
3. The method of claim 1 , further comprising the step of introducing an inert gas into the reaction chamber, wherein the inert gas is selected from the group consisting of He, Ar, Xe, Kr, Ne and N 2 .
4. The method of claim 1 , wherein the film is a silicon-containing film that contains O and/or N and optionally contains dopants B, C, P, As Ga, In, Sn, Sb, Bi and/or Ge, and combinations thereof.
5. The method of claim 1 , wherein the patterned mask layer is an a-C layer, a doped a-C layer, a photoresist layer, an anti-reflective layer, an organic planarization layer, a poly-Si layer, a metal oxide layer including a Ti oxide, an Al oxide, a Zr oxide, a Hf oxide, and combinations thereof.
6. The method of claim 1 , wherein the patterned structure formed in the film has an aspect ratio between approximately 1:1 and approximately 200:1.
7. The method of claim 1 , wherein a conductive sidewall passivation layer is formed on sidewalls of the patterned structure.
8. The method of claim 7 , wherein a conductivity of the conductive sidewall passivation layer formed with the activated C 4 H 2 F 6 and the activated additive compound is at least approximately 10% higher than the conductivity of the conductive sidewall passivation layer formed with the activated C 4 H 2 F 6 without the addition of the activated additive compound.
9. A method for forming a patterned structure, the method comprising the steps:
sequentially or simultaneously exposing a substrate in a reaction chamber to a vapor of C 4 H 2 F 6 and CH 3 I, the substrate having a film disposed thereon and a patterned mask layer disposed on the film;
activating a plasma to produce an activated C 4 H 2 F 6 and an activated CH 3 I; and
allowing an etching reaction to proceed between the film uncovered by the patterned mask layer and the activated C 4 H 2 F 6 and the CH 3 I to selectively etch the film from the patterned mask layer, thereby forming the patterned structure.
10. The method of claim 9 , further comprising the step of introducing an oxidizer into the reaction chamber, wherein the oxidizer is selected from O 2 , O 3 , CO, CO 2 , NO, N 2 O, NO 2 , H 2 O, H 2 O 2 , COS, SO 2 and combinations thereof.
11. The method of claim 9 , further comprising the step of introducing an inert gas into the reaction chamber, wherein the inert gas is selected from the group consisting of He, Ar, Xe, Kr, Ne and N 2 .
12. The method of claim 9 , wherein a conductive sidewall passivation layer is formed on sidewalls of the patterned structure.
13. The method of claim 12 , wherein a conductivity of the conductive sidewall passivation layer formed with the activated C 4 H 2 F 6 and the activated CH 3 I is at least approximately 10% higher than the conductivity of the conductive sidewall passivation layer formed with the activated C 4 H 2 F 6 without the addition of the activated CH 3 I.
14. The method of claim 9 , further comprising introducing an additional etch gas into the reaction chamber, wherein the additional etch gas is selected from the group consisting of cC 4 F 8 , C 4 F 8 , cC 5 F 8 , C 5 F 8 , C 4 F 6 , CF 4 , CH 3 F, CF 3 H, CH 2 F 2 , C 3 HF 7 , C 3 F 6 , C 3 H 2 F 6 , C 3 H 2 F 4 , C 3 H 3 F 5 , C 4 HF 7 , C 5 HF 9 , C 3 F 8 , CF 3 I, C 2 F 3 I, C 2 F 5 I, 1-Iodoheptafluoropropane (1-C 3 F 7 I), 2-Iodoheptafluoropropane (2-C 3 F 7 I), COS, FNO, F—C═N, CS 2 , SO 2 , SF 6 , trans-1,1,1,4,4,4-hexafluoro-2-butene (trans-C 4 H 2 F 6 ), cis-1,1,1,4,4,4-hexafluoro-2-butene (cis-C 4 H 2 F 6 ), hexafluoroisobutene (C 4 H 2 F 6 ), trans-1,1,2,2,3,4-hexafluorocyclobutane (trans-C 4 H 2 F 6 ), 1,1,2,2,3-pentafluorocyclobutane (C 4 H 3 F 5 ), 1,1,2,2-tetrafluorocyclobutane (C 4 H 4 F 4 ), and cis-1,1,2,2,3,4-hexafluorocyclobutane (cis-C 4 H 2 F 6 ), and combinations thereof.
15. A method for forming a patterned structure, the method comprising the steps:
sequentially or simultaneously exposing a substrate to a vapor of C 4 H 2 F 6 and CH 3 I, the substrate having a film disposed thereon and a patterned mask layer disposed on the film;
activating a plasma to produce an activated C 4 H 2 F 6 and an activated CH 3 I; and
allowing an etching reaction to proceed between the film uncovered by the patterned mask layer and the activated C 4 H 2 F 6 and the CH 3 I to selectively etch the film from the patterned mask layer, thereby forming the patterned structure, wherein the patterned structure formed in the film has an aspect ratio between approximately 1:1 and approximately 200:1.