IP Library Granted Patent US 11,772,965
Granted Patent B2
US 11,772,965 · App. 17/138,107 · Granted Oct 3, 2023

Aluminum slurry fuels and their methods of use

Inventors: Jason Fischman (Stamford, CT); Peter Godart (Cambridge, MA); Douglas P. Hart (Charlestown, MA); Andrew Whitehead (Somerville, MA); Jean Sack (Eureka, CA); Eric Morgan (Bolton, MA)
Assignee: Massachusetts Institute of Technology
C01B3/08B01J8/085B01J2208/00761H01M8/0606
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Quick Facts
Patent No.
US 11,772,965
App. No.
17/138,107
Granted
Oct 3, 2023
Kind
B2
Abstract

A stable aluminum slurry fuel and related systems and methods of use are provided herein. Certain embodiments of the disclosure are related to an aluminum slurry fuel comprising a plurality of aluminum particles dispersed in a carrier fluid. In some embodiments, the aluminum particles comprise an activating composition comprising gallium and/or indium. Additionally, methods of making and using the aluminum slurry fuel are presented herein. For instance, the resultant aluminum slurry fuel may react exothermically with water over a wide range of temperatures to produce hydrogen. The resulting slurry fuel may be used as an energy source for various applications and/or for generating hydrogen for other applications.

Claims (30)

1. An aluminum slurry fuel, comprising:

a carrier fluid; and

a plurality of activated aluminum particles dispersed in the carrier fluid, wherein the activated aluminum particles comprise aluminum combined with gallium and/or indium, and wherein the activated aluminum particles are substantially inert relative to the carrier fluid.

2. The aluminum slurry fuel of claim 1 , wherein the carrier fluid is an oil.

3. The aluminum slurry fuel of claim 2 , wherein the oil comprises a viscous oil.

4. The aluminum slurry fuel of claim 2 , wherein the oil comprises a silicone oil.

5. The aluminum slurry fuel of claim 2 , wherein the oil comprises mineral oil.

6. The aluminum slurry fuel of claim 2 , further comprising an additive that acts as a thickener of the oil.

7. The aluminum slurry fuel of claim 6 , wherein the aluminum slurry fuel is configured to exhibit shear thinning properties in the presence of the additive.

8. The aluminum slurry fuel of claim 6 , wherein the additive comprises fumed silica.

9. The aluminum slurry fuel of claim 1 , further comprising 1 wt % to 4 wt % of fumed silica based on a total weight of the aluminum slurry fuel.

10. The aluminum slurry fuel of claim 1 , wherein the plurality of activated aluminum particles has an average size between or equal to 100 μm and 500 μm.

11. The aluminum slurry fuel of claim 1 , wherein a weight percentage of the plurality of activated aluminum particles in the aluminum slurry fuel is between or equal to 10 wt % and 90 wt % based on a total weight of the aluminum slurry fuel.

12. The aluminum slurry fuel of claim 11 , wherein the weight percentage of the plurality of activated aluminum particles in the aluminum slurry fuel is between or equal to 10 wt % and 70 wt % based on the total weight of the aluminum slurry fuel.

13. A power system comprising:

a reactor including the aluminum slurry fuel of claim 1 disposed therein.

14. A method of generating power, the method comprising:

mixing the aluminum slurry fuel of claim 1 with water, wherein a reaction of the plurality of activated aluminum particles with the water releases hydrogen; and

using the hydrogen in a power system to generate power.

15. The aluminum slurry fuel of claim 1 , wherein the carrier fluid has a viscosity between or equal to 50 cSt and 10,000 cSt.

16. A method of using an aluminum slurry fuel, comprising:

mixing an aluminum slurry fuel with water, wherein the aluminum slurry fuel comprises a carrier fluid and a plurality of activated aluminum particles dispersed in the carrier fluid, wherein the activated aluminum particles comprise aluminum combined with gallium and/or indium, and wherein the activated aluminum particles are substantially inert relative to the carrier fluid.

17. The method of claim 16 , wherein the carrier fluid has a viscosity between or equal to 50 cSt and 10,000 cSt.

18. The method of claim 16 , further comprising reacting the plurality of activated aluminum particles with the water to generate hydrogen.

19. The method of claim 16 , wherein the oil comprises a silicone oil and/or a mineral oil.

20. The method of claim 16 , wherein the aluminum slurry fuel further comprises fumed silica.

21. The method of claim 20 , wherein the aluminum slurry fuel comprises 1 wt % to 4 wt % of fumed silica based on a total weight of the aluminum slurry fuel.

22. The method of claim 16 , wherein a weight percentage of the plurality of activated aluminum particles in the aluminum slurry fuel is between or equal to 10 wt % and 90 wt % based on a total weight of the aluminum slurry fuel.

23. The method of claim 22 , wherein the weight percentage of the plurality of activated aluminum particles in the aluminum slurry fuel is between or equal to 10 wt % and 70 wt % based on the total weight of the aluminum slurry fuel.

24. The method of claim 16 , wherein the plurality of activated aluminum particles has an average size between or equal to 100 μm and 500 μm.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 21, 2023
From: FISCHMAN, JASON; GODART, PETER; HART, DOUGLAS P.; WHITEHEAD, ANDREW; SACK, JEAN; MORGAN, ERIC
To: MASSACHUSETTS INSTITUTE OF TECHNOLOGY
Reel/Frame 064355/0874 →
Continuity (2)
Provisional Application 62984113 · Mar 2, 2020
Related Publication 20210316987A1 · Oct 14, 2021
Cited By (1)
US 12,674,412